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Harlamova29_29 [7]
3 years ago
12

Chlorine gas can be made from the reaction of manganese dioxide with hydrochloric acid. MnO2(s) + 4HCl(aq) → MnCl2(aq) + 2H2O(l)

+ Cl2(g) According to the above reaction, determine the limiting reactant when 5.6 moles of
Chemistry
1 answer:
Marina CMI [18]3 years ago
7 0

Answer:

Please see the complete formt of the question below

Chlorine gas can be made from the reaction of manganese dioxide with hydrochloric acid.

MnO₂(s) + HCl(aq) → MnCl₂(aq) + H₂O(l) + Cl₂(g)

According to the above reaction, determine the limiting reactant when 5.6 moles of MnO₂ are reacted with 7.5 moles of HCl.

The answer to the above question is

The limiting reactant is the MnO₂

Explanation:

To solve this,  we note that one mole of MnO₂ reacts with one mole of HCl to produce one mole of MnCl₂, one mole of H₂O and one mole of Cl₂

Molar mass of MnO₂ = 86.9368 g/mol

Molar mass of HCl = 36.46 g/mol

From the stoichiometry of the reaction, 5.6 moles of MnO₂ will react with 5.6 moles of HCl to produce 5.6  moles of H₂O and 5.6 moles of Cl₂

However there are 7.5 moles of HCL therefore there will be an extra 7.5-5.6 or 1.9 moles of HCl remaining when the reaction is completed

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Lewis structures for the perchlorate ion (ClO4−) can be drawn with all single bonds or with one, two, or three double bonds. Dra
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The most important resonance structure is 4 (attached picture). Its bon order is \frac{7}{4} or 1\frac{3}{4}.

Explanation:

A picture with 4 forms of the perchlorate structure is attached. The first structure has simple bonds. The second structure contains a double bond, the third structure has two double bonds and the fourth structure has three double bonds.

Formal charge = group number of the periodic table - number of bonds (number of bonding electrons / 2) - number of non-shared electrons (lone pairs)

The formal charges in the first structure is +3 in chlorine and -1 in oxygen.

The formal charges in the second structure is +2 in chlorine, -1 in oxygen and 0 in the double bond oxygen.

The formal charges in the third structure is +1 in chlorine, -1 in the single bond oxygens and 0 in the double bond oxygens.

The formal charges in the fourth structure is 0 in chlorine, -1 in the single bond oxygen and 0 in the double bond oxygens.

The most important resonance structure is given by:

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Hence, the fourth structure is the mosr important.

The bond order of the structure is:

Total number of bonds: 7

Total number of bond groups: 4

Bond order= \frac{7}{4} =1\frac{3}{4}

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