According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

The formation reaction of $C_2H_4$ will be,

$2C(s)+2H_2(g)\rightarrow C_2H_4(g)$ $\Delta H_{formation}=?$

The intermediate balanced chemical reaction will be,

(1) $C_2H_4(g)+3O_2(g)\rightarrow 2CO_2(g)+2H_2O(l)$ $\Delta H_1=-1411kJ$

(2) $C(s)+O_2(g)\rightarrow CO_2(g)$ $\Delta H_2=-393.5kJ$

(3) $H_2(g)+\frac{1}{2}O_2(g)\rightarrow H_2O(l)$ $\Delta H_3=-285.8kJ$

Now we will reverse the reaction 1, multiply reaction 2 and 3 by 2 then adding all the equation, we get :

(1) $2CO_2(g)+2H_2O(l)\rightarrow C_2H_4(g)+3O_2(g)$ $\Delta H_1=+1411kJ$

(2) $2C(s)+2O_2(g)\rightarrow 2CO_2(g)$ $\Delta H_2=2\times (-393.5kJ)=-787kJ$

(3) $2H_2(g)+2O_2(g)\rightarrow 2H_2O(l)$ $\Delta H_3=2\times (-285.8kJ)=-571.6kJ$

The expression for enthalpy of formation of $C_2H_4$ will be,

$\Delta H_{formation}=\Delta H_1+\Delta H_2+\Delta H_3$

$\Delta H=(+1411kJ)+(-787kJ)+(-571.6kJ)$

$\Delta H=52.4kJ$

Therefore, the standard enthalpy of formation of ethylene is, 52.4 kJ

7 0

2 years ago

The Lewis dot notation for two atoms is shown.

Iteru [2.4K]

Answer:

Mg donates two electrons to O

Explanation:

Lewis dot notation uses dots and crosses to represent valence electrons on atoms.

Magnesium is a metal and would donate or lose electrons during bonding.

Oxygen is a non metal and would gain electrons during bonding.

The correct option is;

Mg donates two electrons to O

5 0

2 years ago

What determines density?

LUCKY_DIMON [66]

Answer:

D = m/v.

Explanation:

The density of a substance is the relationship between the mass of the substance and how much space it takes up (volume). The mass of atoms, their size, and how they are arranged determine the density of a substance. Density equals the mass of the substance divided by its volume;

5 0

2 years ago

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