If we consider a combustion reaction of Methane:
The balanced equation is:
CH4 + 2O2 ---> 2H2O + CO2
The rate of appearance of H2O is rH2O, rate of disappearance of O2 is -rO2
(rH2O)^2 = (-rO2)^2
rH2O = -rO2
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Answer: pH = 3.15
Explanation: Solved in the attached picture.