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4 years ago

Balance the equation :

Chemistry

1 answer:

Sati [7]4 years ago

3 0

The balanced equation is 2 AlI 3 ( a q ) + 3 Cl 2 ( g ) → 2 AlCl 3 ( a q ) + 3 I 2 ( g ) .

Explanation:

Aluminum has a typical oxidation condition of 3+ , and that of iodine is 1- . Along these lines, three iodides can bond with one aluminum. You get AlI3. For comparable reasons, aluminum chloride is AlCl3.

Chlorine and iodine both exist normally as diatomic components, so they are Cl2( g ) also, I2( g ), individually. In spite of the fact that I would anticipate that iodine should be a strong.

Balancing the equation, we get:

2AlI 3( aq ) + 3Cl2 ( g ) → 2AlCl3 ( aq ) + 3 I 2 ( g )

Realizing that there were two chlorines on the left, I simply found the basic numerous of 2 and 3 to be 6, and multiplied the AlCl 3 on the right.

Normally, presently we have two Al on the right, so I multiplied the AlI 3 on the left. Hence, I have 6 I on the left, and I needed to significantly increase I 2 on the right.

We should note, however, that aluminum iodide is viciously receptive in water except if it's a hexahydrate. In this way, it's most likely the anhydrous adaptation broke down in water, and the measure of warmth created may clarify why iodine is a vaporous item, and not a strong.

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Find the pH during the titration of 20.00 mL of 0.1000 M butanoic acid, CH3CH2CH2COOH (K a = 1.54 × 10 − 5), with 0.1000 M NaOH

Zina [86]

Here is the full question

Find the pH during the titration of 20.00 mL of 0.1000 M butanoic acid, CH3CH2CH2COOH (K a = 1.54 × 10 − 5), with 0.1000 M NaOH solution after the following additions of titrant (total volume of added base given):

a) 10.00 mL

pH =

b) 20.10 mL

pH =

c) 25.00 mL

pH =

Answer:

pH = 4.81

pH = 10.40

pH = 12.04

Explanation:

Number of moles of butanoic acid

= $20.00 \ mL * \frac{L}{1000 \ mL} * \frac{0.1000 \ mol}{ L}$

= 0.002000 mol

Number of moles of NaOH added

= $10.00 \ mL * \frac{L}{1000 \ mL }* \frac{0.1000 \ mol }{L}$

= 0.001000 mol

pKa of butanoic acid = - log Ka

= - log ( 1.54 × 10⁻⁵)

= 4.81

Equation for the reaction is expressed as follows:

CH₃CH₂CH₂COOH + OH⁻ -----> CH₃CH₂COO⁻ + H₂O

The ICE Table is expressed as follows:

CH₃CH₂CH₂COOH + OH⁻ -----> CH₃CH₂COO⁻ + H₂O

Initial 0.002000 0.001000 0

Change - 0.001000 - 0.001000 + 0.001000

Equilibrium 0.001000 0 0.001000

Total Volume = (20.00 + 10.00 ) mL

= 30.00 mL = 0.03000 L

Concentration of [CH₃CH₂CH₂COOH] = $\frac{0.001000 \ mol}{ 0.03000 \ L }$

= 0.03333 M

Concentration of [CH₃CH₂COO⁻] = $\frac{0.001000 \ mol}{ 0.03000 \ L}$

= 0.03333 M

By Henderson- Hasselbalch equation

pH = pKa + log $\frac{conjugate \ base}{acid }$

pH = pKa + log $\frac{CH_3CH_2CH_2COO^-}{CH_3CH_2CH_2COOH}$

PH = 4.81 + log $\frac{0.03333}{0.03333}$

pH = 4.81

Thus; the pH of the resulted buffer solution after 10.00 mL of NaOH was added = 4.81

b )

After the equivalence point, we all know that the pH of the solution will now definitely be determined by the excess H⁺

Number of moles of butanoic acid

= $20.00 \ mL * \frac{L}{1000 \ mL} * \frac{0.1000 \ mol}{ L}$

= 0.002000 mol

Number of moles of NaOH added

= $20.10 \ mL * \frac{L}{1000 \ mL} * \frac{0.1000 \ mol}{ L}$

= 0.002010 mol

Following the previous equation of reaction , The ICE Table for this process is as follows:

CH₃CH₂CH₂COOH + OH⁻ -----> CH₃CH₂COO⁻ + H₂O

Initial 0.002000 0.002010 0

Change - 0.002000 -0.002000 + 0.002000

Equilibrium 0 0.000010 0.002000

We can see here that the base is present in excess;

NOW, number of moles of base present in excess

= ( 0.002010 - 0.002000) mol

= 0.000010 mol

Total Volume = (20.00 + 20.10 ) mL

= 40.10 mL × $\frac{1 \ L}{1000 \ mL }$

= 0.04010 L

Concentration of acid [OH⁻] = $\frac{0.000010 \ mol}{0.04010 \ L }$

= $2.494*10^{-4} M$

Using the ionic product of water:

$[H_3O^+] = \frac{K \omega }{[OH^-]}$

where

$K \omega = 10^{-14}$

$[H_3O^+] = \frac{1.0*10^{-14}}{2.494*10^{-14}}$

= $4.0*10^{-11}M$

pH = - log $[H_3O^+}]$

pH = - log [ $4.0*10^{-11}M$ ]

pH = 10.40

Thus, the pH of the solution after the equivalence point = 10.40

After the equivalence point, pH of the solution is determined by the excess H⁺.

Number of moles of butanoic acid

= $20.00 \ mL * \frac{L}{1000 \ mL} * \frac{0.1000 \ mol}{ L}$

= 0.002000 mol

Number of moles of NaOH added

= $25.00 \ mL * \frac{L}{1000 \ mL} * \frac{0.1000 \ mol}{ L}$

= 0.002500 mol

From our chemical equation; The ICE Table can be illustrated as follows:

CH₃CH₂CH₂COOH + OH⁻ -----> CH₃CH₂COO⁻ + H₂O

Initial 0.002000 0.002500 0

Change - 0.002000 -0.002000 +0.002000

Equilibrium 0 0.000500 0.002000

Base is present in excess

Number of moles of base present in excess = [ 0.002500 - 0.002000] mol

= 0.000500 mol

Total Volume = ( 20.00 + 25.00 ) mL

= 45.00 mL

= 45.00 × $\frac{1 \ L}{1000 \ mL }$

= 0.04500 L

Concentration of acid [OH⁻] = $\frac{0.0005000 \ mol}{ 0.04500 \ L }$

= 0.01111 M

Using the ionic product of water $[H_3O^+] = \frac{K \omega }{[OH^+]}$

= $\frac{1.0*10^{-14}}{0.01111}$

= $9.0*10^{-13}$ M

pH = - log $[H_3O^+}]$

pH = - log [ $9.0*10^{-13}M$ ]

pH = 12.04

Thus, the pH of the solution after the equivalence point = 12.04

4 0

3 years ago

A student placed 10.5 g of glucose (C6H12O6) in a volumetric fla. heggsk, added enough water to dissolve the glucose by swirling

aniked [119]

Answer: The mass of glucose in final solution is 0.420 grams

Explanation:

To calculate the molarity of solution, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}$ .........(1)

Initial mass of glucose = 10.5 g

Molar mass of glucose = 180.16 g/mol

Volume of solution = 100 mL

Putting values in equation 1, we get:

$\text{Initial molarity of glucose}=\frac{10.5\times 1000}{180.16\times 100}\\\\\text{Initial molarity of glucose}=0.583M$

To calculate the molarity of the diluted solution, we use the equation:

$M_1V_1=M_2V_2$

where,

$M_1\text{ and }V_1$ are the molarity and volume of the concentrated glucose solution

$M_2\text{ and }V_2$ are the molarity and volume of diluted glucose solution

We are given:

$M_1=0.583M\\V_1=20.0mL\\M_2=?M\\V_2=0.5L=500mL$

Putting values in above equation, we get:

$0.583\times 20=M_2\times 500\\\\M_2=\frac{0.583\times 20}{500}=0.0233M$

Now, calculating the mass of final glucose solution by using equation 1:

Final molarity of glucose solution = 0.0233 M

Molar mass of glucose = 180.16 g/mol

Volume of solution = 100 mL

Putting values in equation 1, we get:

$0.0233=\frac{\text{Mass of glucose in final solution}\times 1000}{180.16\times 100}\\\\\text{Mass of glucose in final solution}=\frac{0.0233\times 180.16\times 100}{1000}=0.420g$

Hence, the mass of glucose in final solution is 0.420 grams

3 0

4 years ago

Hydrogen bonding is a type of intermolecular force that exists between polar covalent molecules, one of which has a hydrogen ato

Luda [366]

It would probably be True

4 0

3 years ago

If have a volume of 18 L of a gas at a temperature of 272 K and a pressure of 90 atm, what will be the pressure of the gas if ra

Solnce55 [7]

Answer:

P₂ ≅ 100 atm (1 sig. fig. based on the given value of P₁ = 90 atm)

Explanation:

Given:

P₁ = 90 atm P₂ = ?

V₁ = 18 Liters(L) L₂ = 12 Liters(L)

=> decrease volume => increase pressure

=> volume ratio that will increase 90 atm is (18L/12L)

T₁ = 272 Kelvin(K) T₂ = 274 Kelvin(K)

=> increase temperature => increase pressure

=> temperature ratio that will increase 90 atm is (274K/272K)

n₁ = moles = constant n₂ = n₁ = constant

P₂ = 90 atm x (18L/12L) x (274K/272K) = 135.9926471 atm (calculator)

By rule of sig. figs., the final answer should be rounded to an accuracy equal to the 'measured' data value having the least number of sig. figs. This means P₂ ≅ 100 atm based on the given value of P₁ = 90 atm.

3 0

3 years ago

If there are 94 different kinds of naturally occurring atoms how many different naturally occurring elements are there?

Delicious77 [7]

Answer:

118 elements

Explanation:

Of these 118 elements, 94 occur naturally on Earth.

7 0

3 years ago