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vaieri [72.5K]
3 years ago
15

Nitrogen dioxide is a red-brown gas responsible for the brown color of smog. A container of nitrogen dioxide that is at low pres

sure and at room temperature has a volume of 3.41L. After more nitrogen dioxide is added, the container holds 2.28×10−2mol of nitrogen dioxide and the volume of the container is 5.11L, still at the same pressure and temperature. How many moles of nitrogen dioxide were in the container initially? Give your answer in three significant figures.
Chemistry
1 answer:
____ [38]3 years ago
8 0

Answer:

Initially 1.51\times 10^{-2} moles of nitrogen dioxide were in the container .

Explanation:

Volume of the container at low pressure and at room temperature =V_1=3.4 L

Number of moles in the container = n_1

After more addition of nitrogen gas at the same pressure and temperature.

Volume of the container after addition = V_2=5.11 L

Number of moles in the container after addition=n_2=2.28\times 10^{-2} mol

Applying Avogadro's law:

\frac{Volume}{Moles}=constant (at constant pressure and temperature)

\frac{V_1}{n_1}=\frac{V_2}{n_2}

n_1=\frac{V_1\times n_2}{V_2}=\frac{3.4 L\times 2.28\times 10^{-2} mol}{5.11 L}

n_1=1.51\times 10^{-2} mol

Initially 1.51\times 10^{-2} moles of nitrogen dioxide were in the container .

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<h3>Further explanation</h3>

The equilibrium constant is the value of the product in the equilibrium state of the substance in the right (product) divided by the substance in the left (reactant) with the exponents of each reaction coefficient

The equilibrium constant is based on the concentration (Kc) in a reaction

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\displaystyle Kc=\frac{0.75.0.75}{0.2.0.2}\\\\Kc=14.1

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initially      0.2   0.2       0.75+x  0.75

reaction    0.1    0.1        0.1         0.1

product     0.3   0.3       0.65+x    0.65

\displaystyle Kc=\frac{(0.650+x)(0.65)}{0.3.0.3}\\\\14.1(0.09)=0.4225+0.65x\\\\1.269-0.4225=0.65x\\\\0.8465=0.65x\\\\x=1.302

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