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lakkis [162]
3 years ago
13

GIVING BRAINLIEST One mole of hydrogen gas (H2), reacts with one mole of bromine Br2(g) to produce 2 moles of hydrogen bromide g

as (HBr). The reaction releases 72.58 kJ of heat. Which equation is the correct form to show the standard molar enthalpy of formation?
H2(g) + Br2(l) → 2HBr(g) ΔHf0= -145.16 kJ

A.1/2H2(g) + Br2(l) → HBr(g) ΔHf0= -72.58 kJ

B.H2(g) + Br2(l)→ HBr(g) ΔHf0= -36.29 kJ

C.1/2 H2(g) + Br2(l) → HBr(g) ΔHf0= -72.58 kJ

D.1/2H2(g) + Br2(l) → HBr(g)ΔHf0= -36.29 kJ
Chemistry
1 answer:
JulsSmile [24]3 years ago
4 0

Answer:

The equation to show the the correct form to show the standard molar enthalpy of formation:

\frac{1}{2}H_2(g) +\frac{1}{2}Br_2(l)\rightarrow HBr(g) ,\Delta H_{f}^o= -36.29 kJ

Explanation:

The standard enthalpy of formation or standard heat of formation of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements, with all substances in their standard states.

Given, that 1 mole of H_2 gas and 1 mole of Br_2 liquid gives 2 moles of HBr gas as a product.The reaction releases 72.58 kJ of heat.

H_2(g) + Br_2(l)\rightarrow 2HBr(g) ,\Delta H_{f}^o= -72.58kJ

Divide the equation by 2.

\frac{1}{2}H_2(g) +\frac{1}{2}Br_2(l)\rightarrow HBr(g) ,\Delta H_{f}^o= -36.29 kJ

The equation to show the the correct form to show the standard molar enthalpy of formation:

\frac{1}{2}H_2(g) +\frac{1}{2}Br_2(l)\rightarrow HBr(g) ,\Delta H_{f}^o= -36.29 kJ

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Answer:

the ion present in the original solution is Ca2+

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⇒The only possible ion that can form a precipate with Cl- is Ag+; since there is no precipitate formed, Ag+ is not present

<u>Step2</u> : If we add Na2SO4 to the solution, a white precipitate is formed

The possible ions to bind at SO42- are Ca2+ and Fe2+

But the white precipitate formed, points in the direction of Ca2+

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<u>Step3</u> : If we add Na2CO3 to the filtered solution, there is a precipate formed

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Identify the oxidized and reduced forms from the following pairs:
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Answer:

1. NAD⁺ is the oxidized form and NADH  is the reduced form

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3. Oxaloacetate is the oxidized form and Malate is the reduced form.

4. Fumarate is the oxidized form and Succinate is the reduced form.

5. FMN is the oxidized form and FMNH₂  is the reduced form

6. α-ketoglutarate is the oxidized form and Isocitrate is the reduced form.

7. O₂ is the oxidized form and  H₂O₂ is the reduced form.

Explanation:

Oxidation is the gain of oxygen or loss of electrons or hydrogen. Whereas, reduction is the loss of oxygen or gain of electrons or hydrogen.

1. NAD⁺/NADH

<u>NAD⁺ is the oxidized form and NADH  is the reduced form of Nicotinamide adenine dinucleotide, NAD.</u>

Therefore, NAD⁺ gets reduced to NADH by accepting electrons and proton.

NAD⁺ + 2 e⁻ + H⁺ → NADH

2. Pyruvate/lactate

Pyruvate, CH₃COCOO⁻, is the conjugate base of Pyruvic acid.

Lactate, CH ₃CH(OH)COO⁻, is the conjugate base of Lactic acid.

Reduction of Pyruvate to lactate:

CH₃COCOO⁻ + NADH  ⇌ CH ₃CH(OH)COO⁻ + NAD⁺

This reaction is catalyzed by the enzyme lactate dehydrogenase.

<u>Therefore, Pyruvate is the oxidized form and Lactate is the reduced form.</u>

3. Malate/oxaloacetate

Oxaloacetate, ⁻O₂CC(O)CH₂CO₂⁻, is the conjugate base of oxaloacetic acid.

Malate,⁻O₂CCH(OH)CH₂CO₂⁻, is the conjugate base of Malic acid.

Oxidation of Malate to Oxaloacetate:

⁻O₂CCH(OH)CH₂CO₂⁻ + NAD⁺  ⇌ ⁻O₂CC(O)CH₂CO₂⁻ + NADH

This reaction is catalyzed by the enzyme malate dehydrogenase.

<u>Therefore, Oxaloacetate is the oxidized form and Malate is the reduced form.</u>

4. Fumarate/succinate

Fumarate, ⁻O₂CCH=CHCO₂⁻, is the conjugate base of Fumaric acid.

Succinate, ⁻O₂CCH₂CH₂CO₂⁻, is the conjugate base of Succinic acid.

Oxidation of succinate to fumarate:

⁻O₂CCH₂CH₂CO₂⁻ + FAD ⇌ ⁻O₂CCH=CHCO₂⁻ + FADH₂

This reaction is catalyzed by the enzyme succinate dehydrogenase.

<u>Therefore, fumarate is the oxidized form and succinate is the reduced form.</u>

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5. FMN/FMNH₂

<u>FMN is the oxidized form and FMNH₂  is the reduced form</u> of riboflavin-5′-phosphate or Flavin mononucleotide.

Therefore, FMN gets reduced to FMNH₂  by accepting electrons and proton.

FMN + 2 e⁻ + 2H⁺ → FMNH₂

     

6. α-ketoglutarate/isocitrate

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Isocitrate, ⁻O₂CCH(OH)CH(CO₂⁻)CH₂CO₂⁻, is the conjugate base Isocitric acid.

Oxidation of Isocitrate to α-ketoglutarate:

⁻O₂CCH(OH)CH(CO₂⁻)CH₂CO₂⁻ + NAD⁺ → ⁻O₂CC(O)CH₂CH₂CO₂⁻ + CO₂ + NADH

This reaction is catalyzed by the enzyme Isocitrate dehydrogenase.

<u>Therefore, α-ketoglutarate is the oxidized form and Isocitrate is the reduced form.</u>

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7. H₂O₂/O₂

Hydrogen peroxide, H₂O₂, is synthesized from hydrogen (H₂) and oxygen (O₂) in the presence of a catalyst.

H₂ + O₂ → H₂O₂

Oxygen gets reduced from 0 oxidation state in O₂ to -1 oxidation state in H₂O₂.

<u>Therefore, O₂ is the oxidized form and  H₂O₂ is the reduced form.</u>

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Explanation:

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c=0.25 M

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