Answer:
159 mg caffeine is being extracted in 60 mL dichloromethane
Explanation:
Given that:
mass of caffeine in 100 mL of water = 600 mg
Volume of the water = 100 mL
Partition co-efficient (K) = 4.6
mass of caffeine extracted = ??? (unknown)
The portion of the DCM = 60 mL
Partial co-efficient (K) = 
where; 
solubility of compound in the organic solvent and 
= solubility in aqueous water.
So; we can represent our data as:
÷ 
Since one part of the portion is A and the other part is B
A+B = 60 mL
A+B = 0.60
A= 0.60 - B
4.6=
÷ 
4.6 = 
4.6 × =
4.6 B 
= 0.6 - B
2.76 B = 0.6 - B
2.76 + B = 0.6
3.76 B = 0.6
B = 
B = 0.159 g
B = 159 mg
∴ 159 mg caffeine is being extracted from the 100 mL of water containing 600 mg of caffeine with one portion of in 60 mL dichloromethane.
Answer:
a. 4,00L
b. 16,00L
c. 12,31L
Explanation:
Avogadro's law says:
a. If initial conditions are 2,30mol and 8,00L and you lose one-half of atoms, that means you have 1,15mol:
<em>V₂ = 4,00L</em>
b. If initial conditions are 2,30mol and 8,00L and you add 2,30mol, that means you have 4,60mol:
<em>V₂ = 16,00L</em>
c. 25,0g of Ne are:
25,0g × (1mol / 20,1797g) = 1,24 moles of Ne. That means you have 2,30mol - 1,24mol = 3,54mol of Ne
<em>V₂ = 12,31L</em>
I hope it helps!
Answer:
The other electron must have anticlockwise spin.
Explanation:
According to the pauli exclusion principle, the two elecrton present in same orbital must have opposite spin.
If the one electron is clockwise the other must be in anti clockwise direction. The clockwise direction is represented by the sign +1/2 while anti clockwise direction is represented by -1/2.
According the pauli principle, the two electrons must have different fourth electronic quantum number. The electron in same orbital have same first three quantum number i.e, n=1 l=0 and ml =0 in case of first subshell.
Answer : The rate constant at 785.0 K is, 
Explanation :
According to the Arrhenius equation,
or,
![\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7BK_1%7D%29%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= rate constant at 
= 
= rate constant at 
= ?
= activation energy for the reaction = 262 kJ/mole = 262000 J/mole
R = gas constant = 8.314 J/mole.K
= initial temperature =
= final temperature =
Now put all the given values in this formula, we get:
![\log (\frac{K_2}{6.1\times 10^{-8}s^{-1}})=\frac{262000J/mole}{2.303\times 8.314J/mole.K}[\frac{1}{600.0K}-\frac{1}{785.0K}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BK_2%7D%7B6.1%5Ctimes%2010%5E%7B-8%7Ds%5E%7B-1%7D%7D%29%3D%5Cfrac%7B262000J%2Fmole%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B600.0K%7D-%5Cfrac%7B1%7D%7B785.0K%7D%5D)
Therefore, the rate constant at 785.0 K is,
6.52 × 10⁴ L. (3 sig. fig.)
<h3>Explanation</h3>
Helium is a noble gas. The interaction between two helium molecules is rather weak, which makes the gas rather "ideal."
Consider the ideal gas law:
,
where
is the pressure of the gas,
is the volume of the gas, 
is the number of gas particles in the gas, 
is the ideal gas constant, and
is the absolute temperature of the gas in degrees Kelvins.
The question is asking for the final volume of the gas. Rearrange the ideal gas equation for volume:
.
Both the temperature of the gas, , and the pressure on the gas changed in this process. To find the new volume of the gas, change one variable at a time.
Start with the absolute temperature of the gas:
,
.
The volume of the gas is proportional to its temperature if both and stay constant.
- won't change unless the balloon leaks, and
- consider to be constant, for calculations that include .
.
Now, keep the temperature at 
and change the pressure on the gas:
,
.
The volume of the gas is proportional to the reciprocal of its absolute temperature 
if both and stays constant. In other words,
(3 sig. fig. as in the question.).
See if you get the same result if you hold constant, change , and then move on to change .
