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Answer:
Explanation:
From the given information:
A → B k₁
B → A k₂
B + C → D k₃
The rate law = ![\dfrac{d[D]}{dt}=k_3[B][C] --- (1)](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%3Dk_3%5BB%5D%5BC%5D%20---%20%281%29)
![\dfrac{d[B]}{dt}=k[A] -k_2[B] -k_3[B][C]](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BB%5D%7D%7Bdt%7D%3Dk%5BA%5D%20-k_2%5BB%5D%20-k_3%5BB%5D%5BC%5D)
Using steady-state approximation;
![\dfrac{d[B]}{dt}=0](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BB%5D%7D%7Bdt%7D%3D0)
![k_1[A]-k_2[B]-k_3[B][C] = 0](https://tex.z-dn.net/?f=k_1%5BA%5D-k_2%5BB%5D-k_3%5BB%5D%5BC%5D%20%3D%200)
![[B] = \dfrac{k_1[A]}{k_2+k_3[C]}](https://tex.z-dn.net/?f=%5BB%5D%20%3D%20%5Cdfrac%7Bk_1%5BA%5D%7D%7Bk_2%2Bk_3%5BC%5D%7D)
From equation (1), we have:
![\mathbf{\dfrac{d[D]}{dt}= \dfrac{k_3k_1[A][C]}{k_2+k_3[C]}}](https://tex.z-dn.net/?f=%5Cmathbf%7B%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_2%2Bk_3%5BC%5D%7D%7D)
when the pressure is high;
k₂ << k₃[C]
![\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_3[C]}= k_1A \ \ \text{first order}](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%20%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_3%5BC%5D%7D%3D%20k_1A%20%5C%20%5C%20%20%5Ctext%7Bfirst%20order%7D)
k₂ >> k₃[C]
![\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_2}= \dfrac{k_1k_3}{k_2}[A][C] \ \ \text{second order}](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%20%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_2%7D%3D%20%5Cdfrac%7Bk_1k_3%7D%7Bk_2%7D%5BA%5D%5BC%5D%20%5C%20%5C%20%20%5Ctext%7Bsecond%20order%7D)
To get the molarity you need to follow this equation
moles of solute
Molarity (M = -----------------------
Liters of solution
But before you apply that equation you need to find the moles of solute and the liters of solution. Follow this equation
Na2SO4 + BaCl2 = BaSO4 + 2 NaCl
Solution
Moles of BaSO4 = 5.28 g
---------------
233.43 g / mol
= 0.0226 moles
Moles of NaSO4 = 0.0226
0.0226 mole
Molarity = -----------------
0.250 L
= 0.0905 mol / L
So the answer is 0.0905 mol / L
Answer:
C. Cs < K < P
Explanation:
Electronegativity is the basically the tendency of an atom to attract electrons. The pauling scale is used to quantify electronegativity, the most electronegative element; fluorine has a value of 4.0 and francium, the least electronegative element has a value of 0.7
The electronegative values of the following elements are given as;
K = 0.82
Cs =0.79
P = 2.19
Arranging in order of increasing electronegativity, we have;
Cs < K < P. The correct option is;
C. Cs < K < P
Answer:
I think it's C sorry if I am wrong
