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Answer : The mass of sodium bromide added should be, 18.3 grams.
Explanation :
Molality : It is defined as the number of moles of solute present in kilograms of solvent.
Formula used :

Solute is, NaBr and solvent is, water.
Given:
Molality of NaBr = 0.565 mol/kg
Molar mass of NaBr = 103 g/mole
Mass of water = 315 g
Now put all the given values in the above formula, we get:


Thus, the mass of sodium bromide added should be, 18.3 grams.
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Option-C: They react mainly by substitution.
Explanation:
Alkene doesn't give substitution reactions because they are non polar in nature. The double bond in alkene is responsible for Electrophillic Addition reactions as it electron rich and nucleophilic in nature. Reaction of Alkene is given below,</span>
(0.48 gram) x (1mole / 4.0 gram) = 0.48/4.0 = 0.12 mole