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masha68 [24]
3 years ago
15

Consider the reaction: CaCO3(s) à CaO(s) + CO2(g)

Chemistry
1 answer:
Vsevolod [243]3 years ago
6 0

Answer:

131.5 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

First, we will calculate the standard enthalpy of the reaction (ΔH°).

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g) ) - 1 mol × ΔH°f(CaCO₃(s) )

ΔH° = 1 mol × (-634.9 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1207.6 kJ/mol)

ΔH° = 179.2 kJ

Then, we calculate the standard entropy of the reaction (ΔS°).

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g) ) - 1 mol × S°(CaCO₃(s) )

ΔS° = 1 mol × (38.1 J/mol.K) + 1 mol × (213.8 J/mol.K) - 1 mol × (91.7 J/mol.K)

ΔS° = 160.2 J/K = 0.1602 kJ/K

Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.

ΔG° = ΔH° - T × ΔS°

ΔG° = 179.2 kJ - 298 K × 0.1602 kJ/K

ΔG° = 131.5 kJ

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<u>larger is the value of </u>Ksp<u> the higher will the solubility of solid in water.</u>

What is called compound?

  • In chemistry, a compound is a substance made up of two or more different chemical elements combined in a fixed ratio.
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The equation for the dissociation of a solid MX in water is given below

MX(s) ⇄ Mⁿ⁺(aq) + Xⁿ⁻ (aq)

Assume s be the solubility of MX in pure water, then the equilibrium concentrations of ions are

[ Mⁿ⁺] = s

[ Xⁿ⁻ ] = s

The expression for the solubility product constant (Ksp) is as follows

Ksp = [ Mⁿ⁺] [ Xⁿ⁻ ]

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A 12.0% sucrose solution by mass has a density of 1.05 gem, what mass of sucrose is present in a 32.0-mL sample of this solution
natulia [17]

Answer:

Option C. 4.03 g

Explanation:

Firstly we analyse data.

12 % by mass, is a sort of concentration. It indicates that in 100 g of SOLUTION, we have 12 g of SOLUTE.

Density is the data that indicates grams of solution in volume of solution.

We need to determine, the volume of solution for the concentration

Density = mass / volume

1.05 g/mL = 100 g / volume

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Therefore our 12 g of solute are contained in 95.24 mL

Let's finish this by a rule of three.

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oksano4ka [1.4K]

Answer : The reagent present in excess and remains unreacted is, O_2

Solution : Given,

Moles of FeCl_3 = 3.00 mole

Moles of O_2 = 2.00 mole

Excess reagent : It is defined as the reactants not completely used up in the reaction.

Limiting reagent : It is defined as the reactants completely used up in the reaction.

Now we have to calculate the limiting and excess reagent.

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