A or C are the best options
The first question's answer is
If more heat is removed from the reaction the rate of reaction change as below to counter the action
The rate of the <em>forward reaction increase</em> and produces more <em>zinc chloride</em>
<u><em> explanation</em></u>
- <u><em> </em></u>The reaction of zinc and HCl to produce ZnCl and H2 <u><em>is </em></u> exothermic reaction, heat is produced as one product and by removing heat it favor forward reaction
- The position of equilibrium moves to the right since removing heat led to decrease of temperature and more zinc chloride is produced.
The solution is as follows:
K = [Partial pressure of isoborneol]/[Partial pressure of borneol] = 0.106
The molar mass of isoborneol/borneol is 154.25 g/mol
Mol isoborneol = 15 g/154.25 = 0.0972 mol
Mol borneol = 7.5 g/154.25 = 0.0486 mol
Use the ICE approach
borneol → isoborneol
I 0.0972 0.0486
C -x +x
E 0.0972 - x 0.0486 + x
Total moles = 0.1458
Using Raoult's Law,
Partial Pressure = Mole fraction*Total Pressure
[Partial pressure of isoborneol] = [(0.0972-x)/0.1458]*P
[Partial pressure of borneol] = [(0.0486+x/0.1458)]*P
0.106 = [(0.0972-x)/0.1458]*P/ [(0.0486+x/0.1458)]*P
Solving for x,
x = 0.0832
Thus,
<em>Mol fraction of borneol = (0.0486+0.0832)/0.1458 = 0.904</em>
<em>Mol fraction of isoborneol = (0.0972-0.0832)/0.1458 = 0.096</em>