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cluponka [151]
3 years ago
13

A balloon is filled to a volume of 5.10l at a temperature of 27.1ºc. if the pressure in the balloon is measured to be 2.20 atm,

how many moles of gas are contained inside the balloon?
Chemistry
1 answer:
Leno4ka [110]3 years ago
5 0
We can find the number of moles in the balloon using the ideal gas law equation 
PV = nrT 
where 
P - pressure - 2.20 atm 
V - volume - 5.10 L
n - number of moles 
r - universal gas constant - 0.08206 LatmK⁻¹mol⁻¹
T - temperature in Kelvin - 27.1 °C + 273 = 300.1 K
substituting the values in the equation 
2.20 atm x 5.10 L = n x 0.08206 LatmK⁻¹mol⁻¹ x 300.1 K
n = 0.456 mol
number of moles of gas is 0.456 mol

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NO + 0.5O2 -----> NO2

Then we write all the reactions,

2O3 -----> 3O2    </span><span>δ h = -426 kj        eq. (1)

O2 -----> 2O    </span><span>δ h = 490 kj             eq. (2)

NO + O3 -----> NO2 + O2    </span><span>δ h = -200 kj          eq. (3)


We divide eq. (1) by 2, we get

</span>O3 -----> 1.5O2    δ h = -213  kj             eq. (4)

Then, we subtract eq. (3) by eq. (4) 

NO + O3 ----->  NO2 + O2   δ h = -200 kj
-       (O3 -----> 1.5 O2         δ h = -213  kj)
NO -----> NO2 - 0.5O2        δ h = 13  kj               eq. (5)


eq. (2) divided by -2. (Note: Dividing or multiplying by negative number reverses the reaction)

O -----> 0.5O2  <span>δ h = -245  kj         eq. (6)
</span>
Add eq. (6) to eq. (5), we get

NO -----> NO2 - 0.5O2        δ h = 13  kj 
+  O -----> 0.5O2                 δ h = -245  kj
NO + O ----> NO2               δ h = -232 kj

<em>ANSWER:</em> <em>NO + O ----> NO2               δ h = -232 kj</em>


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