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leonid [27]
3 years ago
14

The reaction 2a → a2​​​​​ was experimentally determined to be second order with a rate constant, k, equal to 0.0265 m–1min–1. if

the initial concentration of a was 4.25 m, what was the concentration of a (in m) after 180.0 min?
Chemistry
2 answers:
olga nikolaevna [1]3 years ago
7 0
According to the second order formula:
1/[At] = K t + 1/[Ao]
and when we have the K constant =0.0265 & we have t = 180 min & we have the initial concentration of A = 4.25 so by substitution:

1/[At]  = 0.0265 X 180min + 1/4.25 
1/[At] = 5
∴[At] = 1/5 = 0.2 m
andre [41]3 years ago
7 0

Answer : The final concentration was 0.199 M

Explanation :

The expression used for second order kinetics is:

kt=\frac{1}{[A_t]}-\frac{1}{[A_o]}

where,

k = rate constant = 0.0265M^{-1}min^{-1}

t = time = 180.0 min

[A_t] = final concentration = ?

[A_o] = initial concentration = 4.25 M

Now put all the given values in the above expression, we get:

0.0265\times 180.0=\frac{1}{[A_t]}-\frac{1}{4.25}

[A_t]=0.199M

Therefore, the final concentration was 0.199 M

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M_1V_1=M_2V_2

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M_2\text{ and }V_2 are the molarity and volume of diluted solution which is the solution to be prepared.

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2 years ago
In the preparation of a certain alkyl halide, 10 g of sodium bromide (NaBr), 10 mL distilled water (H20), and 9 mL 3-methyl-1-bu
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Percentage yield shows the amount of reactants converted into products. The percentage yield of the reaction is 51.7%.

The equation of the reaction is sown in the image attached. The reaction is 1:1 as we can see.

Number of moles of NaBr = 10 g/103 g/mol = 0.097 moles

We can obtain the mass of 3-methyl-1-butanol from its density.

Mass = density × volume

Density of 3-methyl-1-butanol =  0.810 g/mL

Volume of  3-methyl-1-butanol = 9 mL

Mass of 3-methyl-1-butanol = 0.810 g/mL × 9 mL

Mass of 3-methyl-1-butanol = 7.29 g

Number of moles of 3-methyl-1-butanol =  mass/molar mass =  7.29 g/88 g/mol = 0.083 moles

Since the reaction is 1:1 then the limiting reagent is 3-methyl-1-butanol

Mass of product 1-bromo-3-methylbutane = number of moles × molar mass

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Mass of product 1-bromo-3-methylbutane = 0.083 moles × 151 g/mol

= 12.53 g

Recall that % yield = actual yield/theoretical yield × 100

Actual yield of product = 6.48 g

Theoretical yield = 12.53 g

% yield = 6.48 g/12.53 g × 100

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