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Alik [6]
3 years ago
10

A gas-filled balloon having a volume of 3.60 L at 1.15 atm and 20°C is allowed to rise to the stratosphere (about 30 km above th

e surface of the Earth), where the temperature and pressure are −50°C and 5.40 × 10−3 atm, respectively. Calculate the final volume of the balloon.
Chemistry
1 answer:
MissTica3 years ago
5 0

<u>Answer:</u> The new volume of the balloon will be 583.5 L

<u>Explanation:</u>

To calculate the volume when temperature and pressure has changed, we use the equation given by combined gas law.

The equation follows:

\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}

where,

P_1,V_1\text{ and }T_1 are the initial pressure, volume and temperature of the gas

P_2,V_2\text{ and }T_2 are the final pressure, volume and temperature of the gas

We are given:

P_1=1.15atm\\V_1=3.60L\\T_1=20^oC=[20+273]K=293K\\P_2=5.40\times 10^{-3}atm=0.00540atm\\V_2=?\\T_2=-50^oC=[-50+273]K=223K

Putting values in above equation, we get:

\frac{1.15atm\times 3.60L}{293K}=\frac{0.00540atm\times V_2}{223K}\\\\V_2=\frac{1.15\times 3.60\times 223}{293\times 0.00540}=583.5L

Hence, the new volume of the balloon will be 583.5 L

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Answer: Reaction (1) , (3) and (4) are accompanied by an increase in entropy.

Explanation:

Entropy is the measure of randomness or disorder of a system. If a system moves from  an ordered arrangement to a disordered arrangement, the entropy is said to decrease and vice versa.

(1) 2SO_2(g)+O_2(g)\rightarrow SO_3(g)

3 moles of reactant are changing to 1 mole of product , thus the randomness is increasing. Thus the entropy also increases.

2) H_2O(l)\rightarrow H_2O(s)

1 mole of Liquid reactant is changing to 1 mole of solid product , thus the randomness is decreasing. Thus the entropy also decreases.

3) Br_2(l)\rightarrow Br_2(g)

1 mole of Liquid reactant is changing to 1 mole of gaseous product , thus the randomness is increasing. Thus the entropy also increases.

4)  H_2O_2(l)\rightarrow H_2O(l)+\frac{1}{2}O_2(g)

1 mole of Liquid reactant is changing to half mole of gaseous product and 1 mole of liquid product, thus the randomness is increasing. Thus the entropy also increases.

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Where are elements that form molecules of two of the same atoms commonly found on the periodic table?
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Calculate the volume of carbon dioxide at 20.0°C and 0.941 atm produced from the complete combustion of 4.00 kg of methane. Comp
tankabanditka [31]

Answer:

The volume of carbon dioxide at 20.0°C and 0.941 atm produced was 6390.89 Liters.

More volume of carbon dioxide gas was released on combustion of 4.00 kg of propane in comparison to the volume of carbon dioxide released on combustion of 4.00 kg of methane.

Explanation:

Methane

CH_4+2O_2\rightarrow CO_2+2H_2O

Mass of methane = 4.00 kg = 4000 g (1 kg = 1000 g)

Moles of methane = \frac{4000 g}{16 g/mol}=250 mol

According to reaction, 1 mole of methane gives 1 mole of carbon dioxide gas,then 250 moles of methane will give :

\frac{1}{1}\times 250 mol=250 mol of carbon dioxide gas

Moles of carbon dioxide gas = n = 250 mol

Pressure of carbon dioxide gas = P = 0.941 atm

Temperature of carbon dioxide gas = T = 20.0°C = 20.0+273 K = 293 K

Volume of carbon dioxide gas = V

PV=nRT (Ideal gas equation)

V=\frac{nRT}{P}=\frac{250 mol\times 0.0821 atm L/mol K\times 293 K}{0.941 atm}=6390.89 L

The volume of carbon dioxide at 20.0°C and 0.941 atm produced was 6390.89 Liters.

Propane

C_3H_8+5O_2\rightarrow 3CO_2+4H_2O

Mass of propane = 4.00 kg = 4000 g (1 kg = 1000 g)

Moles of propane = \frac{4000 g}{44 g/mol}=90.91 mol

According to reaction, 1 mole of propane gives 3 mole of carbon dioxide gas,then 90.91 moles of propane will give :

\frac{3}{1}\times 90.91 mol=272.73 mol of carbon dioxide gas

Moles of carbon dioxide gas = n = 272.73 mol

Pressure of carbon dioxide gas = P = 0.941 atm

Temperature of carbon dioxide gas = T = 20.0°C = 20.0+273 K = 293 K

Volume of carbon dioxide gas = V

PV=nRT (Ideal gas equation)

V=\frac{nRT}{P}=\frac{272.73 mol\times 0.0821 atm L/mol K\times 293 K}{0.941 atm}=6,971.95 L

The volume of carbon dioxide at 20.0°C and 0.941 atm produced was 6,971.95 Liters.

Volume of carbon dioxide given by combustion of 4.00 kg of methane = 6390.89 Liters.

Volume of carbon dioxide given by combustion of 4.00 kg of propane = 6,971.95 Liters.

6390.89 Liters < 6,971.95 Liters

More volume of carbon dioxide gas was released on combustion of 4.00 kg of propane in comparison to the volume of carbon dioxide released on combustion of 4.00 kg of methane.

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