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serious [3.7K]
3 years ago
6

A 62.6-gram piece of heated limestone is placed into 75.0 grams of water at 23.1°C. The limestone and the water come to a final

temperature of 51.9°C. The specific heat capacity of water is 4.186 joules/gram degree Celsius, and the specific heat capacity of limestone is 0.921 joules/gram degree Celsius. What was the initial temperature of the limestone? Express your answer to three significant figures.
The initial temperature of the limestone was
Chemistry
1 answer:
alekssr [168]3 years ago
7 0

Answer:

208.7°C was the initial temperature of the limestone.

Explanation:

Heat lost by limestone will be equal to heat gained by the water

-Q_1=Q_2

Mass of limestone = m_1=62.6 g

Specific heat capacity of limestone = c_1=0.921 J/g^oC

Initial temperature of the limestone = T_1=?

Final temperature = T_2=T =  51.9°C

Q_1=m_1c_1\times (T-T_1)

Mass of water= m_2=75.0 g

Specific heat capacity of water= c_2=4.186 J/g^oC

Initial temperature of the water = T_3=23.1^oC

Final temperature of water = T_2=T =  51.9°C

Q_2=m_2c_2\times (T-T_3)

-Q_1=Q_2

-(m_1c_1\times (T-T_1))=m_2c_2\times (T-T_3)

On substituting all values:

-(62.6 g\times 0.921 J/g^oC\times (51.9^oC-T_1))=75.0 g\times 4.186 J/g^oC\times (51.9^oC-23.1^oC)

T_1=208.7^oC

208.7°C was the initial temperature of the limestone.

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Answer: Fe<em>(aq)</em>+S<em>(aq)</em>=FeS<em>(s)</em>

Explanation: The Sodium and Bromine are spectator ions because they don't react with anything, you can see this by writing the ionic equation like so:

1.) Molecular formula (given): FeBr2 (aq)+Na2S (aq)= FeS(s)+2NaBr(aq)

Each dissolved FeBr2 breaks up into one Fe with a charge of 2+ and two Br with a negative charge. This gives you:

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2.) Now repeat what was shown with the other compounds in the given molecular formula, and pay attention to the states that each ion is in (solid, liquid, aqueous, gas) because this will give you the ionic equation, which from there you can get rid of any ions that don't change amount or state.

3.) Ionic formula: Fe(aq)+ <u>2Br(aq)</u>+<u>2 Na(aq)</u>+S (aq)=FeS(s)+<u>2 Na(aq)+2Br(aq)</u>

4.)When you've derived a total ionic equation (above), you'll  find that some ions appear on both sides of the equation in equal numbers. For example, in this case two Na cations and two Br anions appear on both sides of the total ionic equation. What does this mean? It means these ions don't participate in the chemical reaction. They're present before and after the reaction. Nothing happens to them. So those are removed and you're left with the net ionic: Fe(aq)+S(aq)=FeS(s)

Hope this helps :)

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