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serious [3.7K]
3 years ago
6

A 62.6-gram piece of heated limestone is placed into 75.0 grams of water at 23.1°C. The limestone and the water come to a final

temperature of 51.9°C. The specific heat capacity of water is 4.186 joules/gram degree Celsius, and the specific heat capacity of limestone is 0.921 joules/gram degree Celsius. What was the initial temperature of the limestone? Express your answer to three significant figures.
The initial temperature of the limestone was
Chemistry
1 answer:
alekssr [168]3 years ago
7 0

Answer:

208.7°C was the initial temperature of the limestone.

Explanation:

Heat lost by limestone will be equal to heat gained by the water

-Q_1=Q_2

Mass of limestone = m_1=62.6 g

Specific heat capacity of limestone = c_1=0.921 J/g^oC

Initial temperature of the limestone = T_1=?

Final temperature = T_2=T =  51.9°C

Q_1=m_1c_1\times (T-T_1)

Mass of water= m_2=75.0 g

Specific heat capacity of water= c_2=4.186 J/g^oC

Initial temperature of the water = T_3=23.1^oC

Final temperature of water = T_2=T =  51.9°C

Q_2=m_2c_2\times (T-T_3)

-Q_1=Q_2

-(m_1c_1\times (T-T_1))=m_2c_2\times (T-T_3)

On substituting all values:

-(62.6 g\times 0.921 J/g^oC\times (51.9^oC-T_1))=75.0 g\times 4.186 J/g^oC\times (51.9^oC-23.1^oC)

T_1=208.7^oC

208.7°C was the initial temperature of the limestone.

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a) Calculatethe molality, m, of an aqueous solution of 1.22 M sucrose, C12H22O11. The density of the solution is 1.12 g/mL.b) Wh
Contact [7]

Answer:

a) 1,74 molal

b) 37,2 %

c) 0,03

Explanation:

We are going to define sucrose as solute, water as solvent and the mix of both, the solution.

Let´s start with the data:

Molarity = M = \frac{1,22 mol solute}{lts solution}

We can assume as a calculus base, 1 liter of solution. So, in 1 liter of solution we have 1,22 moles of solute:

1 lts solution * \frac{1,22 moles solute}{lts solution}=1,22 moles solute

Knowing that the molality (m) is defined as mol of solute/kgs solvent, we have to calculate the mass of solvent on the solution. Remember our calculus base (1 lts of solution). In 1 lts of solution we have 1120 grams of solution.

1 lts solution * \frac{1,12 grs solution}{mL solution}*\frac{1000 mL solution}{1 lts solution} = 1120 grs of solution

With the molecular weight of solute (<em>Sum of: for carbon = 12*12=144; for hydrogen = 1*22=22 and for oxygen = 16*11=176. Final result = 342 grs per mol</em>), we can obtain the mass of solute:

1,22 mol solute*\frac{342 grs solute}{1 mol solute} = 417,24 grs solute

Now, the mass of solvent is: mass solvent = mass of solution - mass of solute. So, we have: 1120 - 417,24 = 702,76 grs of solvent = 0,70276 Kgs of solvent

molality = m = \frac{1,22 mol solute}{0,70276 kgs solvent}= 1,74 molal

For b) question we have that the mass percent of solute is hte ratio between the mass of solute and the mass of solution. So,

%(w/w) = \frac{417,24 grs solute}{1120 grs solution} = 37,2%

For c) question we have that the mole fraction of solute is the ratio between moles of solute and moles of solution. Let's calculate the moles of solution as follows: <em>Moles solution = moles solute + moles solvent.</em> First we have that the moles of solvent are (remember that the molecular weight of water for this calculus is 18 grs per mol):

702,76 grs solvent*\frac{1 mol solvent}{18 grs solvent} = 39,04 moles solvent  

So, we have the moles of solution: 1,22 moles of solute + 39,04 moles of solvent = 40,26 moles of solution

Finally, we have:

Mol frac solute = \frac{1,22 mol solute}{40,26 mol solution}= 0,03

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