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Semenov [28]
3 years ago
11

Calculate the specific volume of Helium using the compressibility factor. 500 kPa, 60 degrees Celsius

Chemistry
1 answer:
IrinaK [193]3 years ago
7 0

Explanation:

Formula for compressibility factor is as follows.

                     z = \frac{P \times V_{m}}{R \times T}

where,     z = compressibility factor for helium = 1.0005

               P = pressure

          V_{m} = molar volume

                R = gas constant = 8.31 J/mol.K

                T = temperature

So, calculate the molar volume as follows.

                V_{m} = \frac{z \times R \times T}{P}

                             = \frac{1.0005 \times 8.314 \times 10^{-3} m^{3}.kPa/mol K \times (60 + 273)K}{500 kPa}

                             = 0.0056 m^{3}/mol

As molar mass of helium is 4 g/mol. Hence, calculate specific volume of helium as follows.

                    V_{sp} = \frac{V_{m}}{M_{w}}

                           = \frac{0.0056 m^{3}/mol}{4 g/mol}

                           = 0.00139 m^{3}/g

                           = 0.00139 m^{3}/g \times \frac{1 g}{10^{-3}kg}

                                 = 1.39 m^{3}/kg

Thus, we can conclude that the specific volume of Helium in given conditions is 1.39 m^{3}/kg.

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Explanation:

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Determine the pH of 0.050 M HCN solution. HCN is a weak acid with a Ka equal to 4.9 x 10-10<br> DONE
nadezda [96]

Answer:

The pH of the solution is 5.31.

Explanation:

Let "\alpha is the dissociation of weak acid - HCN.

The dissociation reaction of HCN is as follows.

                  HCN+H_{2}O\rightarrow H_{3}O^{+}+CN^{-}

Initial                  C                         0            0

Equilibrium        c(1- \alpha)              c\alpha c\alpha

Dissociation constant = Ka= c\alpha \times \frac{c\alpha}{c(1-\alpha)}

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In this case weak acids \alpha is very small so, (1-\alpha ) is taken as 1.

Ka=C\alpha^{2}

\alpha=\sqrt\frac{ka}{c}

From the given the concentration = 0.050 M

Substitute the given value.

\alpha=\sqrt\frac{4.9\times 10^{-10}}{0.05}=9.8\times 10^{-4}

[H_{3}O^{+}]=c\alpha

[H_{3}O^{+}]=0.05\times 9.8\times 10^{-4}= 4.9\times10^{-6}

pH= -log[H_{3}O^{+}]

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=6-log 4.9= 5.31

Therefore, The pH of the solution is 5.31.

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3 years ago
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Answer:

The answers are as given in the attachment

Explanation:

The application of the de brogile equation was used and appropriate substitution were made as shown in the attachment

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