Answer : The correct option is, (D) 3600 kJ
Explanation :
Mass of octane = 75 g
Molar mass of octane = 114.23 g/mole
Enthalpy of combustion = -5500 kJ/mol
First we have to calculate the moles of octane.
Now we have to calculate the heat released in the reaction.
As, 1 mole of octane released heat = -5500 kJ
So, 0.656 mole of octane released heat = 0.656 × (-5500 kJ)
= -3608 kJ
≈ -3600 kJ
Therefore, the heat released in the reaction is 3600 kJ
The structure of the alkyl bromides used in a malonic ester synthesis of ethyl 2-methyl-4-pentenoate are as drawn in the attached image.
<h3>Ethyl 2-methyl-4-pentenoate by Malonic ester synthesis.</h3>The malonic ester synthesis is a chemical reaction characterized by the alkylation of diethyl malonate or a similar ester of malonic acid at the carbon alpha (directly adjacent) to both carbonyl groups, and subsequently converted to a substituted acetic acid.
Hence, it follows from the structure of Ethyl 2-methyl-4-pentenoate that the alkyl bromides used are Ethyl bromide and methyl bromide.
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