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3 years ago

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A buffer solution is made that is 0.417 M in and 0.417 M in . If for is , what is the pH of the buffer solution? pH = Write the

net ionic equation for the reaction that occurs when 0.120 mol is added to 1.00 L of the buffer solution. (Use the lowest possible coefficients. Omit states of matter.)

1 answer:

cricket20 [7]3 years ago

6 0

Answer:

pH = 3.347

NO₂⁻ + H₃O⁺ → HNO₂

Explanation:

If the buffer is made with 0.417M of HNO₂ and 0.417M of NaNO₂ the pH of the solution is = pKa. <em>A buffer which concentration of weak acid and conjugate base is the same has a pH = pKa</em>

As Ka of the solution is 4.50x10⁻⁴, pKa is -log 4.50x10⁻⁴ = 3.347. Thus,<em> pH = 3.347</em>

<em />

The net ionic equation that occurs when 0.120 mol of HCl is added to 1.00L of the solution is:

<em>NO₂⁻ + H₃O⁺ → HNO₂ + H₂O</em>

<em>The conjugate base (NaNO₂) reacts with strong acid (HCl, source of H₃O⁺) producing weak acid (HNO₂) and water. If a strong base is added, the weak acid reacts producing conjugate base and water.</em>

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Aqueous concentrated nitric acid is 69% hno3 by weight and has a density of 1.42 g/ml.

OleMash [197]

Answer: -

15.55 M

35.325 molal

Explanation: -

Let the volume of the solution be 1000 mL.

Density of nitric acid = 1.42 g/ mL

Total Mass of nitric acid Solution = Volume of nitric acid x Density of nitric acid

= 1000 mL x 1.42 g/ mL

= 1420 g.

Percentage of HNO₃ = 69%

Amount of HNO₃ = $\frac{69} {100} x 1420 g$

= 979.8 g

Molar mass of HNO₃ = 1 x 1 + 14 x 1 + 16 x 3 = 63 g /mol

Number of moles of HNO₃ = $\frac{979.8 g}{63 g/ mol}$

= 15.55 mol

Molarity is defined as number of moles per 1000 mL

We had taken 1000 mL as volume and found it to contain 15.55 moles.

Molarity of HNO₃ = 15.55 M

Mass of water = Total mass of nitric acid solution - mass of nitric acid

= 1420 - 979.8

= 440.2 g

So we see that 440.2 g of water contains 15.55 moles of HNO₃

Molality is defined as number of moles of HNO₃ present per 1000 g of water.

Molality of HNO₃ = $\frac{15.55 x 1000}{440.2}$

= 35.325 molal

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Does seeing a gas produced always mean a chemical reaction is occurring? Explain.

chubhunter [2.5K]

Seeing signs of a chemical reaction does not always mean that a reaction is happening. For example, a gas (water vapor) is given off when water boils. ... You can tell that it is a physical change because water vapor can condense to form liquid water. In a chemical change, a new substance must be produced.

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A complex, ML₆²⁺, is violet. The same metal forms a complex with another ligand, Q, that creates a weaker field. What color migh

Bingel [31]

A complex, ML₆²⁺, is violet. The same metal forms a complex with another ligand, Q, that creates a weaker field. MQ₆²⁺, be expected to show green color.

<h3>What is spectrochemical series?</h3>

The ligands (attachment to a metal ion) are listed in the spectrochemical series according to the strength of their field. The series has been created by superimposing several sequences discovered through spectroscopic research because it is impossible to produce the full series by examining complexes with a single metal ion. The halides are referred to be weak-field ligands whereas the ligands cyanide and CO are strong-field ligands. Medium field effects are claimed to be produced by ligands like water and ammonia.

To know more about the spectrochemical series, visit:

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1 year ago

1. The solubility of lead(II) chloride at some high temperature is 3.1 x 10-2 M. Find the Ksp of PbCl2 at this temperature.

solniwko [45]

Answer:

1) The solubility product of the lead(II) chloride is $1.2\times 10^{-4}$ .

2) The solubility of the aluminium hydroxide is $1.6\times 10^{-10} M$ .

3)The given statement is false.

Explanation:

1)

Solubility of lead chloride = $S=3.1\times 10^-2M$

$PbCl_2(aq)\rightleftharpoons Pb^{2+}(aq)+2Cl^-(aq)$

S 2S

The solubility product of the lead(II) chloride = $K_{sp}$

$K_{sp}=[Pb^{2+}][Cl^-]^2$

$K_{sp}=S\times (2S)^2=4S^3=4\times (3.1\times 10^{-2})^3=1.2\times 10^{-4}$

The solubility product of the lead(II) chloride is $1.2\times 10^{-4}$ .

2)

Concentration of aluminium nitrate = 0.000010 M

Concentration of aluminum ion = $1\timed 0.000010 M=0.000010 M$

Solubility of aluminium hydroxide in aluminum nitrate solution = $S$

$Al(OH)_3(aq)\rightleftharpoons Al^{3+}(aq)+3OH^-(aq)$

S 3S

The solubility product of the aluminium nitrate = $K_{sp}=1.0\times 10^{-33}$

$K_{sp}=[Al^{3+}][OH^-]^3$

$1.0\times 10^{-33}=(0.000010+S)\times (3S)^3$

$S=1.6\times 10^{-10} M$

The solubility of the aluminium hydroxide is $1.6\times 10^{-10} M$ .

3.

$Molarity=\frac{Moles}{Volume (L)}$

Mass of NaCl= 3.5 mg = 0.0035 g

1 mg = 0.001 g

Moles of NaCl = $\frac{0.0035 g}{58.5 g/mol}=6.0\times 10^{-5} mol$

Volume of the solution = 0.250 L

$[NaCl]=\frac{6.0\times 10^{-5} mol}{0.250 L}=0.00024 M$

1 mole of NaCl gives 1 mole of sodium ion and 1 mole of chloride ions.

$[Cl^-]=[NaCl]=0.00024 M$

Moles of lead (II) nitrate = n

Volume of the solution = 0.250 L

Molarity lead(II) nitrate = 0.12 M

$n=0.12 M]\times 0.250 L=0.030 mol$

1 mole of lead nitrate gives 1 mole of lead (II) ion and 2 moles of nitrate ions.

$[Pb^{2+}]=[Pb(NO_2)_3]=0.030 M$

$PbCl_2(aq)\rightleftharpoons Pb^{2+}(aq)+2Cl^-(aq)$

Solubility of lead(II) chloride = $K_{sp}=1.2\times 10^{-4}$

Ionic product of the lead chloride in solution :

$Q_i=[Pb^{2+}][Cl^-]^2=0.030 M\times (0.00024 M)^2=1.7\times 10^{-9}$

$Q_i$ ( no precipitation)

The given statement is false.

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4 years ago

Salts are which part of an aqueous solution?

masha68 [24]

Explanation:

Salts are the solutes in an aqueous solution. An aqueous solution is solution whose solvent water.

To form a solution,a solute must be dissolved in a solvent.
For aqueous solutions, the solvent which is the dissolving medium is made up of water.
The solute is the substance that is dissolved in it.
Salts for example can be a solute in an aqueous solution.
A salt is generally an ionic compound consisting of positive ions such as metallic, ammonium ans complex ions and negative ions such as acid radicals and complex ions.

Learn more:

Aqueous solution brainly.com/question/8426727

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