Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Answer:
aldehyde
carbon-1
ketone
carbon-2
Explanation:
Monosaccharides are colorless crystalline solids that are very soluble in water. Moat have a swwet taste. D-Fructose is the sweetest monosaccharide.
In the open chain form, monosaaccharides have a carbonuyl group in one of their chains. If the carbonyl group is in the form of an aldehyde group, the monosaccharide is an aldose; if the carbonyl group is in the form of a ketone group, the monosaccharide is known as a ketose. glucose is an aldose while fructose is a ketose.
In D-glucose, there is an aldehyde functional group, and the carbonyl group is at carbon-1 when looking at the Fischer projection.
In D-fructose, there is a ketone functional group, and the carbonyl group is at carbon-2 when looking at the Fischer projection.
Explanation:
The degree of unsaturation is given as;
Degree of unsaturation = (2C + 2 + N - H - X) / 2
(a) C5H6
Using the formular above;
Degree of unsaturation = [ 2(5) + 2 - 6] / 2
Degree of unsaturation = [ 12 - 6 ] / 2 = 3
(b) C10H6Cl2
Using the formular above;
Degree of unsaturation = [ 2(10) + 2 - 6 -2 ] / 2
Degree of unsaturation = [ 22 - 8 ] / 2 = 7
(c) C4H3NO
Using the formular above;
Degree of unsaturation = [ 2(4) + 2 - 3 -1 ] / 2
Degree of unsaturation = [ 10 - 4 ] / 2 = 3
Note: Oxygen is ignored because its presence has no effect on the degree of unsaturation.
