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emmainna [20.7K]
3 years ago
5

One of the reagents below gives predominantly 1,2 addition (direct addition) while the other gives predominantly 1,4 addition (c

onjugate addition). a) Which major organic product is the result of 1,2 addition? ---Select--- b) Draw the skeletal structure of major organic product A

Chemistry
2 answers:
Hunter-Best [27]3 years ago
4 0

Complete Question

The complete question is shown on the first uploaded image

Answer:

a

The correct option is reagent B

b

The  skeletal structure of major organic product A is shown on the third uploaded image

Explanation:

The mechanism of the reaction for A and  B  are shown on the second the second reaction and looking at this we can see that the reagent that  predominately gives 1,2 addition is reagent B  

Gala2k [10]3 years ago
4 0

Answer:

The complete question is shown on the first uploaded image

Answer:

a

The correct option is reagent B

b

The  skeletal structure of major organic product A is shown on the third uploaded image

Explanation:

The mechanism of the reaction for A and  B  are shown on the second the second reaction and looking at this we can see that the reagent that  predominately gives 1,2 addition is reagent B  

Explanation:

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3 years ago
A water solution contains 1.704 [kg] of HNO3 per [kg] of water, and has a specific gravity of 1.382 at 20 [°C]. Please, express
Rudik [331]

Answer:

(a) The weight percent HNO3 is 63%.

(b) Density of HNO3 = 111.2 lb/ft3

(c) Molarity = 13792 mol HNO3/m3

Explanation:

(a) Weight percent HNO3

To calculate a weight percent of a component of a solution we can express:

wt = \frac{mass \, of \, solute}{mass \, of \, solution}=\frac{mass\,HNO_3}{mass \, HNO_3+mass \, H_2O}\\  \\wt=\frac{1.704}{1.704+1} =\frac{1.704}{2.704}= 0.63

(b) Density of HNO3, in lb/ft3

In this calculation, we use the specific gravity of the solution (1.382). We can start with the volume balance:

V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}+\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{2.956/ \rho_w}= 0.576*\rho_w[tex]V_s=V_{HNO3}+V_w\\\\\frac{M_s}{\rho_s}=\frac{M_{HNO3}}{\rho_{HNO3}}+\frac{M_w}{\rho_w}\\\\\frac{M_{HNO3}}{\rho_{HNO3}} = \frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}\\\\\rho_{HNO3}=\frac{M_{HNO3}}{\frac{M_s}{\rho_s}-\frac{M_w}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{\frac{2.704}{1.382*\rho_w}-\frac{1}{\rho_w}} \\\\ \rho_{HNO3}=\frac{1.704}{0.956/\rho_w}= 1.782*\rho_w

The density of HNO3 is 1.782 times the density of water (Sp Gr of 1.782). If the density of water is 62.4 lbs/ft3,

\rho_{HNO3}= 1.782*\rho_w=1.782*62.4 \, lbs/ft3=111.2\, lbs/ft3

(c) HNO3 molarity (mol HNO3/m3)

If we use the molar mass of HNO3: 63.012 g/mol, we can say that in 1,704 kg (or 1704 g) of HNO3 there are  1704/63.012=27.04 mol HNO3.

When there are 1.704 kg of NHO3 in solution, the total mass of the solution is (1.704+1)=2.704 kg.

If the specific gravity of the solution is 1.382 and the density of water at 20 degC is 998 kg/m3, the volume of the solution is

Vol=\frac{M_{sol}}{\rho_{sol}}=\frac{2.704\, kg}{1.382*998 \, kg/m3} = 0.00196m3

We can now calculate the molarity as

Molarity HNO_3=\frac{MolHNO3}{Vol}=\frac{27.04mol}{0.00196m3}  =13792 \frac{molHNO3}{m3}

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The rate of disappearance of HCl was measured for the following reaction:
AURORKA [14]

Answer: (a)  0.000083M/s,  0.000069M/s, 0.000052M/s,  0.000034M/s

(b) average reaction rate between t=0.0min to t=430.0min =0.000049M/s

(c) The average rate between t=54.0 and t=215.0min is greater than the average rate between t=107.0 and t=430.0min

Explanation:

Average reaction rate = change in concentration / time taken

(a) <em>after 54mins, t = 54*60s = 3240s</em>

average reaction rate = (1.58 - 1.85)M / (3240 * 0.0)s

= -0.27M/3240

= 0.000083M/s

<em>after 107mins, t = 107*60s = 6420s</em>

average reaction rate = (1.36 - 1.58)M/ (6420 - 3240)s

= -0.22M/3180s

= 0.000069M/s

<em>after 215mins, t = 215*60s = 12900s</em>

average reaction rate = (1.02 - 1.36)M/ (12900 - 6420)s

= -0.34M/6480s

= 0.000052M/s

<em>after 430mins,t = 430*60 = 25800s</em>

average reaction rate = (0.580 - 1.02)M / (25800 - 12900)s

= -0.44M/12900s

= 0.000034M/s

(b) <em>average reaction rate between t=0.0min to t=430.0min</em>

= (0.580 - 1.85)M/ (25800 - 0.0)s

= -1.27M/25800s

=0.000049M/s

(c) average reaction rate between t = 54.0min and t = 215.0min

= (1.02 - 1.58)M / (12900 - 3240)s

= -0.56M/9660s

= 0.000058M/s

average reaction rate between t=107.0 and t=430.0min

= (0.580 - 1.36)M / (25800 - 6420)s

= 0.78M /19380s

= 0.000040M/s

Therefore the average rate between t=54.0 and t=215.0min is greater than the average rate between t=107.0 and t=430.0min

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3 years ago
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