Explanation:
According to the Henderson-Hasselbalch equation, the relation between pH and 
is as follows.
pH = 
where, pH = 7.4 and = 7.21
As here, we can use the nearest to the desired pH.
So, 7.4 = 7.21 + 
0.19 =
= 1.55
1 mM phosphate buffer means ![[HPO_{4}]](https://tex.z-dn.net/?f=%5BHPO_%7B4%7D%5D)
+ ![[H_{2}PO_{4}]](https://tex.z-dn.net/?f=%5BH_%7B2%7DPO_%7B4%7D%5D)
= 1 mM
Therefore, the two equations will be as follows.
= 1.55 ............. (1)
+ = 1 mM ........... (2)
Now, putting the value of from equation (1) into equation (2) as follows.
1.55![[H_{2}PO_{4}] + [tex][H_{2}PO_{4}]](https://tex.z-dn.net/?f=%5BH_%7B2%7DPO_%7B4%7D%5D%20%2B%20%5Btex%5D%5BH_%7B2%7DPO_%7B4%7D%5D)
= 1 mM
2.55 = 1 mM
= 0.392 mM
Putting the value of in equation (1) we get the following.
0.392 mM + = 1 mM
= (1 - 0.392) mM
= 0.608 mM
Thus, we can conclude that concentration of the acid must be 0.608 mM.
This question is describing the following chemical reaction at equilibrium:
And provides the relative amounts of both A and B at 25 °C and 75 °C, this means the equilibrium expressions and equilibrium constants can be written as:
Thus, by recalling the Van't Hoff's equation, we can write:
Hence, we solve for the enthalpy change as follows:
Finally, we plug in the numbers to obtain:
![\Delta H=\frac{-8.314\frac{J}{mol*K} *ln(0.25/9)}{[\frac{1}{(75+273.15)K} -\frac{1}{(25+273.15)K} ] } \\\\\\\Delta H=4,785.1\frac{J}{mol}](https://tex.z-dn.net/?f=%5CDelta%20H%3D%5Cfrac%7B-8.314%5Cfrac%7BJ%7D%7Bmol%2AK%7D%20%2Aln%280.25%2F9%29%7D%7B%5B%5Cfrac%7B1%7D%7B%2875%2B273.15%29K%7D%20-%5Cfrac%7B1%7D%7B%2825%2B273.15%29K%7D%20%5D%20%7D%20%5C%5C%5C%5C%5C%5C%5CDelta%20H%3D4%2C785.1%5Cfrac%7BJ%7D%7Bmol%7D)
Learn more:
The correct answer for the following questions that are presented above are these ones:
(1) b. Pressure. The <span>physical effect can change the boiling point of a substance is the pressure.
(2) </span><span>Evaporation only occurs at the surface of a liquid. TRUE.</span><span>
(3) </span>d. freezing. The change from liquid to solid, or the reverse of melting, is called freezing.
N₂ + 3H₂ ⇒ 2NH₃
doesnt matterN₂ + 6.64H₂ ⇒ 2NH₃
(6.64H₂/3H₂) x (2NH₃) =4.4266667
rounded to sig figs= 4.43
I believe Winter is <span>your answer.</span>
