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-Dominant- [34]
3 years ago
7

For Mn3+, write an equation that shows how the cation acts as an acid.

Chemistry
2 answers:
Mkey [24]3 years ago
8 0

An acid is a compound which will give H+ ions or H3O^+  ions

the reaction will be

[Mn(H_{2}O )_{6} ^{+3} +H_{2}O --> [MnOH(H_{2}O)_{5}]^{+2} + H_{3}O^{+}

Thus as there is evolution of H_{3}O^{+} the Mn+3 is an acid

yuradex [85]3 years ago
7 0

The equation that shows {\text{M}}{{\text{n}}^{3 + }}  acts as the acid is

\boxed{{{\left[{{\text{Mn}}{{\left({{{\text{H}}_2}{\text{O}}}\right)}_6}}\right]}^{3 + }}+{{\text{H}}_2}{\text{O}}\to{{\left[ {{\text{MnOH}}{{\left({{{\text{H}}_2}{\text{O}}} \right)}_5}}\right]}^{2 + }}{{\text{H}}_3}{{\text{O}}^ + }}

Further Explanation:

Acids and bases can be defined in many ways based on different theories, which are as follows:

1. Arrhenius theory: According to this theory, acid is defined as the one which produces hydrogen or hydronium ions in a solution, while the base is defined as the one which produces hydroxide ions in a solution. Examples of Arrhenius acids include HBr, {\text{HN}}{{\text{O}}_3} and  {{\text{H}}_2}{\text{S}}{{\text{O}}_4} while NaOH and KOH are examples of Arrhenius bases.

2. Bronsted-Lowry theory: According to this theory, the acid in the reaction donates a proton while a base is one that accepts a proton. HCl acts as Bronsted acid while {\text{N}}{{\text{H}}_3} is a Bronsted base.

3. Lewis theory: According to this theory, an acid accepts a pair of electrons to electron-rich species while a base donates electrons to electron-deficient species in the reaction. Examples of Lewis acids are {\text{B}}{{\text{F}}_3} , {\text{S}}{{\text{O}}_3} while {{\text{H}}_2}{\text{O}} and ROH are the examples of Lewis base.

The equation to show the acidic nature of {\mathbf{M}}{{\mathbf{n}}^{{\mathbf{3 + }}}} is as follows:

{\left[ {{\text{Mn}}{{\left({{{\text{H}}_2}{\text{O}}}\right)}_6}}\right]^{3 + }}+{{\text{H}}_2}{\text{O}}\to {\left[{{\text{MnOH}}{{\left( {{{\text{H}}_2}{\text{O}}}\right)}_5}} \right]^{2+}}+{{\text{H}}_3}{{\text{O}}^+}

Here, {\text{M}}{{\text{n}}^{3 + }} exists as {\left[{{\text{Mn}}{{\left( {{{\text{H}}_2}{\text{O}}}\right)}_6}}\right]^{3 + }} in the aqueous medium. It reacts with water molecule to form {\left[{{\mathbf{MnOH}}{{\left( {{{\mathbf{H}}_{\mathbf{2}}}{\mathbf{O}}} \right)}_{\mathbf{5}}}} \right]^{{\mathbf{2 + }}}} and {{\mathbf{H}}_{\mathbf{3}}}{{\mathbf{O}}^{\mathbf{ + }}} is also released during the reaction.

Learn more:

1. The reason for the acidity of water brainly.com/question/1550328

2. Reason for the acidic and basic nature of amino acid brainly.com/question/5050077

Answer details:

Grade: High School

Subject: Chemistry

Chapter: Chemical reaction and equation

Keywords: acid, Mn3+, Arrhenius theory, Bronsted-Lowry theory, Lewis theory, H3O+, HCl, NH3, BF3, SO3, hydrogen ions, hydronium ions, hydroxide ions, aqueous, water, Mn(H20)63+, MnOH(H2O)63+, H2O, accepts, donates, electrons, reaction, proton.

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valentinak56 [21]

Answer : The value of \Delta G_{rxn} is, 8.867kJ/mole

Explanation :

The formula used for \Delta G_{rxn} is:

\Delta G_{rxn}=\Delta G^o+RT\ln Q   ............(1)

where,

\Delta G_{rxn} = Gibbs free energy for the reaction

\Delta G_^o =  standard Gibbs free energy

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T = temperature = 25^oC=273+25=298K

Q = reaction quotient

First we have to calculate the \Delta G_^o.

Formula used :

\Delta G^o=-RT\times \ln K_p

Now put all the given values in this formula, we get:

\Delta G^o=-(8.314J/mole.K)\times (298K)\times \ln (2.26\times 10^{4})

\Delta G^o=-24839.406J/mole=-24.83\times 10^3J/mole=-24.83kJ/mole

Now we have to calculate the value of 'Q'.

The given balanced chemical reaction is,

CO(g)+2H_2(g)\rightarrow CH_3OH(g)

The expression for reaction quotient will be :

Q=\frac{(p_{CH_3OH})}{(p_{CO})\times (p_{H_2})^2}

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

Q=\frac{(1.4)}{(1.2\times 10^{-2})\times (1.2\times 10^{-2})^2}

Q=8.1\times 10^{5}

Now we have to calculate the value of \Delta G_{rxn} by using relation (1).

\Delta G_{rxn}=\Delta G^o+RT\ln Q

Now put all the given values in this formula, we get:

\Delta G_{rxn}=-24.83kJ/mole+(8.314\times 10^{-3}kJ/mole.K)\times (298K)\ln (8.1\times 10^{5})

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Therefore, the value of \Delta G_{rxn} is, 8.867kJ/mole

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