The overall reaction is given by:
The fast step reaction is given as:
The slow step reaction is given as:
(slow step 
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
![r_{2}=k_{2}[NOBr_{2}] [NO]](https://tex.z-dn.net/?f=r_%7B2%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%20%5BNO%5D)
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as ![[NOBr_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D)
takes place in this reaction.
The expression of rate of formation is:
= ![k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of 
in terms of reactants is given by .
Answer:
The 
solution has a higher osmotic pressure and higher boiling point than LiCl solution.
Explanation:
As concentrations of two aqueous solutions are same therefore we can write:
, 
and 
where 
, 
and 
are lowering of vapor pressure, elevation in boiling point and osmotic pressure of solution respectively. 
is van't hoff factor.
= total number of ions generated from dissolution of one molecule of a substance (for strong electrolyte).
Here both and LiCl are strong electrolytes.
So, 
and 
Hence, lowering of vapor pressure, elevation in boiling point and osmotic pressure will be higher for solution.
Therefore the solution has a higher osmotic pressure and higher boiling point than LiCl solution.
Explanation:
N2O4(g) <----------> 2NO2(g)
Before proceeding,
A chemical equilibrium can be defined as a condition in the course of a reversible chemical reaction in which no net change in the amounts of reactants and products occurs.
Statement 1.
This statement is false. Equilibrium is not about equal concentrations but rather zero change in concentration of the reactants and products.
Statement 2.
This statement is True in chemical equilibrium; the forward and reverse reactions occur at equal rates.
Statement 3.
This statement is False. The rate constant for the forward reaction is not equal to the rate constant of the reverse reaction.
Statement 4.
The concentration of NO2 divided by the concentration of N2O4 is NOT equal to a constant. To obtain a constant value irregardless of the concentrations, the concentration of NO2 must be squared. This comes from the stoichiometry of the reaction
Kc= [NO2]2 / [N2O4]
This statement is false.
In 313 CE, the emperor Constantine issued the Edict of Milan, which granted Christianity as well as most other religions legal status.
