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saw5 [17]
3 years ago
9

Calculate the molarity of 0.850 mol of Na2S in 1.70 L of solution.

Chemistry
1 answer:
Basile [38]3 years ago
5 0

Molarity is simply the ratio of the number of moles of a substance over the total volume of the solution. Assuming that the addition of 0.850 moles does not change the overall volume of 1.70 L, therefore molarity is simply:

 

Molarity = 0.850 moles / 1.70 L = 0.5 moles / L = 0.5 M

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The spectator ions is: K^+   and  SO^{2-}_4

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H_2SO_{4(aq)} + 2KOH _{aq} \to K_2SO_{4(aq)} +2H_2O _{(l)}

Rewriting this equation as ionic;

[2H^{+} + SO^{2-}_4 + 2K^+ +2OH^- \to 2K^+  SO_4^{2-} + 2H_2O ]

Spectators ions are ions present on both sides of the ionic equation by the same quantity but do not take part in the net reaction.

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"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"
Andru [333]

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

<em>Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical</em>

<em />

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

  • <em>pKa NH₃/NH₄⁺</em>

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = <em>4.74</em>

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

  • <em>Moles NH₃</em>

<em>2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃</em>

  • <em>H-H equation:</em>

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

<h3>245.66g of NH₄Cl is the mass we need to add to obtain the desire pH</h3>

<em />

3 0
4 years ago
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