Answer : The pH of the solution is, 9.63
Explanation : Given,
The dissociation constant for HCN = 
First we have to calculate the moles of HCN and NaCN.

and,

The balanced chemical reaction is:

Initial moles 0.1116 0.0461 0.08978
At eqm. (0.1116-0.0461) 0 (0.08978+0.0461)
0.0655 0.1359
Now we have to calculate the pH of the solution.
Using Henderson Hesselbach equation :
![pH=pK_a+\log \frac{[Salt]}{[Acid]}](https://tex.z-dn.net/?f=pH%3DpK_a%2B%5Clog%20%5Cfrac%7B%5BSalt%5D%7D%7B%5BAcid%5D%7D)
Now put all the given values in this expression, we get:


Therefore, the pH of the solution is, 9.63
Answer:
"1.4 mL" is the appropriate solution.
Explanation:
According to the question,
Now,
Increase in volume will be:
⇒ 
By putting the given values, we get



B boiling point https://chem.libretexts.org/Bookshelves/Introductory_Chemistry/Map%3A_Introductory_Chemistry_(Tro)/03%3A_Matter_and_Energy/3.05%3A_Differences_in_Matter%3A_Physical_and_Chemical_Properties#Summary
The answer should be A.
Hope this helps :-)