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NARA [144]
3 years ago
14

Calculate the hight of a column of liquid glycerol in meters required to exert the same pressure as 3.02 m if CCl4?

Chemistry
1 answer:
katovenus [111]3 years ago
4 0

Answer:

Approximately 3.81\; \rm m.

Explanation:

Look up the density \rho of carbon tetrachloride, \rm CCl_4, and glycerol:

  • Density of carbon tetrachloride: approximately 1.59\times 10^{3}\; \rm kg \cdot m^{-3}.
  • Density of glycerol: approximately 1.26\times 10^{3}\; \rm kg \cdot m^{-3}.

Let g denote the gravitational field strength. (Typically g \approx 9.81\; \rm N \cdot kg^{-1} near the surface of the earth.) For a column of liquid with a height of h, if the density of the liquid is \rho, the pressure at the bottom of the column would be:

P = \rho\cdot g \cdot h.

The pressure at the bottom of this carbon tetrachloride column would be:

\begin{aligned} P &= \rho \cdot g \cdot h \\ & \approx 1.59\times 10^{3} \; \rm kg \cdot m^{-3} \times 9.81\; \rm N \cdot kg^{-1} \times 3.02 \; \rm m \approx 4.71 \times 10^{4} \; \rm N \cdot m^{-2} \end{aligned}.

Rearrange the equation P = \rho\cdot g \cdot h for h:

\displaystyle h = \frac{P}{\rho \cdot g}.

Apply this equation to calculate the height of the liquid glycerol column:

\begin{aligned}h &= \frac{P}{\rho \cdot g} \\ &\approx \frac{4.71 \times 10^{4}\; \rm N \cdot m^{-2}}{1.26 \times 10^{3}\; \rm kg \cdot m^{-3} \times 9.81\; \rm N \cdot kg^{-1}} \approx 3.81\; \rm m\end{aligned}.

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7 0
3 years ago
Fill in the blanks with the correct term.
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Answer:

Fill in the blanks with the correct term.

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a. A liquid that dissolves another substance is called the solvent.

b. A chemical that is dissolved solute.

c. A value used to describe the amount of one substance dissolved in another is called concentration.

d. A liquid consisting of one substance dissolved in another is called a solution.

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3 years ago
1. Using the Slater rule, determine the effective nuclear charge of platinum.
AleksandrR [38]

Answer:

Z* = 3.55

Explanation:

Slater rule says that:

Z*= Z - S

Z* be the nuclear effective charge

Z is the nuclear charge

S is the shielding constant

First we write the electronic configuration of platinum:1s^{2} 2s^{2} 2p^{6} 3s^{2} 3p^{6} 3d^{10} 4s^{2} 4p^{6} 4d^{10} 5s^{2} 5p^{6} 4f^{14} 5d^{9} 6s^{1}

The first Slater rule says that we need to group:

(1s^{2}) (2s, 2p)^{8} (3s, 3p)^{8} (3d^{10}) (4s, 4p)^{8} (4d^{10}) (5s, 5p)^{8} (4f^{14}) (5d^{9}) (6s^{1})

The second rule says that the electrons to the right are not shielding, but we are going to solve the exercise for the last level (6s), so we don't have electrons to the right.

For the third rule we have two considerations, if is ns or np and if is nd or nf:

For our case, we have an electro that is in ns, so the rule says that

-electrons within same group shield 0.35, except the 1s which shield 0.30

-electrons within the n-1 group shield 0.85

-electrons within the n-2 or lower groups shield 1.00

Now we can proceed with the calculation:

The first consideration in the third rule does not apply as we only have one electron on this level.

The second consideration will be as follow for the level 5, where we have 17 electrons.

Finally the third consideration will be for levels 1, 2, 3 and 4, where we have 14 for 4f, 10 for 4d, 8 for 4s and 4p, 10 for 3d, 8 for 3s and 3p, 8 for 2s and 2p and finally 2 for 1s, which gives 60 electrons.

So the result for S=(60*1.00 + 17*0.85) = 74.45

And the equation is: Z* = 78 - 74.45

So Z* = 3.55

3 0
3 years ago
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