The enthalpy change for an exothermic reaction is negative because heat is being released, so that takes out two of the responses. Since energy is being released into the surroundings due to the exothermic reaction, the potential energy of the products is lower than that of the reactants. Energy is being put in to make the reaction occur, but then that energy is all being released into the surroundings thus a lower potential energy level for the products
<u>Answer:</u> The correct statement is low temperature only, because entropy decreases during freezing.
<u>Explanation:</u>
The relationship between Gibb's free energy, enthalpy, entropy and temperature is given by the equation:

Where,
= change in Gibb's free energy
= change in enthalpy
T = temperature
= change in entropy
It is given that freezing of methane is taking place, which means that entropy is decreasing and
is becoming negative. It is also given that the reaction is an exothermic reaction, this means that the
is also negative.
For a reaction to be spontaneous,
must be negative.
![-ve=-ve-[T(-ve)]\\\\-ve=-ve+T](https://tex.z-dn.net/?f=-ve%3D-ve-%5BT%28-ve%29%5D%5C%5C%5C%5C-ve%3D-ve%2BT)
From above equations, it is visible that
will be negative only when the temperature will be low.
Hence, the correct statement is low temperature only, because entropy decreases during freezing.