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WARRIOR [948]
3 years ago
15

A child has a toy balloon with a volume of 1.80 liters. The temperature of the balloon when it was filled was 20° C and the pres

sure was 1.00 atm. If the child were to let go of the balloon and it rose 3 kilometers into the sky where the pressure is 0.667 atm and the temperature is -10° C, what would the new volume of the balloon be? (Don't forget to convert the temperature to K)
Chemistry
1 answer:
kiruha [24]3 years ago
8 0

Answer:

The new volume of the balloon is 2.422 liters.

Explanation:

Let suppose that gas inside the balloon behaves ideally. From the Equation of State for Ideal Gases, we know that pressure (P), in atmospheres, is inversely proportional to volume (V), in liters, and directly proportional to temperature (T), in Kelvin. Based on this fact, we construct the following relationship:

\frac{P_{1}\cdot V_{1}}{T_{1}} = \frac{P_{2}\cdot V_{2}}{T_{2}} (1)

Where:

P_{1}, P_{2} - Initial and final pressures, in atmospheres.

V_{1}, V_{2} - Initial and final volumes, in liters.

T_{1}, T_{2} - Initial and final temperatures, in Kelvin.

If we know that P_{1} = 1\,atm, V_{1} = 1.80\,L, T_{1} = 293.15\,K, P_{2} = 0.667\,atm, T_{2} = 263.15\,K, then the final pressure is:

V_{2} = V_{1} \cdot \left(\frac{P_{1}}{P_{2}} \right)\cdot \left(\frac{T_{2}}{T_{1}} \right)

V_{2} = 2.422\,L

The new volume of the balloon is 2.422 liters.

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Total vapor pressure can be calculated using partial vapor pressures and mole fraction as follows:

P=X_{A}P_{A}+X_{B}P_{B}

Here, X_{A} is mole fraction of A, X_{B} is mole fraction of B, P_{A} is partial pressure of A and P_{B} is partial pressure of B.

The mole fraction of A and B are related to each other as follows:

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In this problem, A is hexane and B is octane, mole fraction of hexane is given 0.580 thus, mole fraction of octane can be calculated as follows:

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