Toluene is subjected to the action of the following reagents in the order given: (1) KMnO4,OH-, heat; then H3O (2) HNO3, H2SO4 (
1 answer:
Answer:
See image attached
Explanation:
The reaction of toluene with alkaline potassium permanganate in the presence of heat leads to the oxidation of the -CH3 to give benzoic acid.
Reaction benzoic acid with HNO3/H2SO4 yields the nitronium ion (NO2+).
Recall that -COOH is a metal director and deactivated the ring towards electrophilic substitution hence the m-nitrobenzoic acid is formed.
Reaction with FeBr3/Br2 yields the product shown in the image attached.
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Answer: -
15.55 M
35.325 molal
Explanation: -
Let the volume of the solution be 1000 mL.
Density of nitric acid = 1.42 g/ mL
Total Mass of nitric acid Solution = Volume of nitric acid x Density of nitric acid
= 1000 mL x 1.42 g/ mL
= 1420 g.
Percentage of HNO₃ = 69%
Amount of HNO₃ =
= 979.8 g
Molar mass of HNO₃ = 1 x 1 + 14 x 1 + 16 x 3 = 63 g /mol
Number of moles of HNO₃ =
= 15.55 mol
Molarity is defined as number of moles per 1000 mL
We had taken 1000 mL as volume and found it to contain 15.55 moles.
Molarity of HNO₃ = 15.55 M
Mass of water = Total mass of nitric acid solution - mass of nitric acid
= 1420 - 979.8
= 440.2 g
So we see that 440.2 g of water contains 15.55 moles of HNO₃
Molality is defined as number of moles of HNO₃ present per 1000 g of water.
Molality of HNO₃ =
= 35.325 molal
Answer : The enthalpy of reaction is, 67.716 KJ/mole
Explanation :
First we have to calculate the moles of and
.
Now we have to calculate the moles of AgCl formed.
The balanced chemical reaction will be,
As, 1 mole of react with 1 mole of
to give 1 mole of
So, 0.005 mole of react with 0.005 mole of
to give 1 mole of
The moles of AgCl formed = 0.005 mole
Total volume of the solution = 50.0 ml + 50.0 ml = 100.0 ml
Now we have to calculate the mass of solution.
Mass of the solution = Density of the solution × Volume of the solution
Mass of the solution = 1.00 g/ml × 100.0 ml = 100 g
Now we have to calculate the heat.
where,
q = heat
C = specific heat capacity =
m = mass = 100 g
= final temperature =
= initial temperature =
Now put all the given values in the above expression, we get:
Now we have to calculate the enthalpy of the reaction.
where,
= enthalpy of reaction = ?
q = heat of reaction = 338.58 J
n = moles of reaction = 0.005 mole
Now put all the given values in above expression, we get:
Conversion used : (1 KJ = 1000 J)
Therefore, the enthalpy of reaction is, 67.716 KJ/mole