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Stells [14]
2 years ago
9

Toluene is subjected to the action of the following reagents in the order given: (1) KMnO4,OH-, heat; then H3O (2) HNO3, H2SO4 (

3) Br2, FeBr3 What is the final product of this sequence?
Chemistry
1 answer:
Shkiper50 [21]2 years ago
5 0

Answer:

See image attached

Explanation:

The reaction of toluene with alkaline potassium permanganate in the presence of heat leads to the oxidation of the -CH3 to give benzoic acid.

Reaction benzoic acid with HNO3/H2SO4 yields the nitronium ion (NO2+).

Recall that -COOH is a metal director and deactivated the ring towards electrophilic substitution hence the m-nitrobenzoic acid is formed.

Reaction with FeBr3/Br2 yields the product shown in the image attached.

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A student is performing a titration to determine the concentration of a 20.0 mL sample of hydrochloric acid. What did the studen
irakobra [83]

Answer:

0.25M HCl

Explanation:

The reaction of HCl with NaOH is:

HCl + NaOH ⇄ H₂O + NaCl

<em>Where 1 mole of HCl reacts per mole of NaOH</em>

The end point was reached when the student added:

0.0500L × (0.1mol / L) = 0.00500 moles of NaOH

As 1 mole of HCl reacted per mole of NaOH, moles of HCl present are:

<em>0.00500 moles HCl</em>

The volume of the sample of hydrochloric acid was 20.0mL = 0.0200L, and concentration of the sample is:

0.00500 mol HCl / 0.0200L = <em>0.25M HCl</em>

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What is the purpose of the prefixes in the metric system?
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<span>Prefixes are used in the metric system to indicate smaller or larger measurements</span>
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Aqueous concentrated nitric acid is 69% hno3 by weight and has a density of 1.42 g/ml.
OleMash [197]

Answer: -

15.55 M

35.325 molal

Explanation: -

Let the volume of the solution be 1000 mL.

Density of nitric acid = 1.42 g/ mL

Total Mass of nitric acid Solution = Volume of nitric acid x Density of nitric acid

= 1000 mL x 1.42 g/ mL

= 1420 g.

Percentage of HNO₃ = 69%

Amount of HNO₃ = \frac{69} {100} x 1420 g

= 979.8 g

Molar mass of HNO₃ = 1 x 1 + 14 x 1 + 16 x 3 = 63 g /mol

Number of moles of HNO₃ = \frac{979.8 g}{63 g/ mol}

= 15.55 mol

Molarity is defined as number of moles per 1000 mL

We had taken 1000 mL as volume and found it to contain 15.55 moles.

Molarity of HNO₃ = 15.55 M

Mass of water = Total mass of nitric acid solution - mass of nitric acid

= 1420 - 979.8

= 440.2 g

So we see that 440.2 g of water contains 15.55 moles of HNO₃

Molality is defined as number of moles of HNO₃ present per 1000 g of water.

Molality of HNO₃ = \frac{15.55 x 1000}{440.2}

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3 0
3 years ago
When you combine 50.0 mL of 0.100 M AgNO3 with 50.0 mL of 0.100 M HCl in a coffee-cup calorimeter, the temperature changes from
RideAnS [48]

Answer : The enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

Explanation :

First we have to calculate the moles of AgNO_3 and HCl.

\text{Moles of }AgNO_3=\text{Molarity of }AgNO_3\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

\text{Moles of }HCl=\text{Molarity of }HCl\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

Now we have to calculate the moles of AgCl formed.

The balanced chemical reaction will be,

AgNO_3(aq)+HCl(aq)\rightarrow AgCl(s)+HNO_3(aq)

As, 1 mole of AgNO_3 react with 1 mole of HCl to give 1 mole of AgCl

So, 0.005 mole of AgNO_3 react with 0.005 mole of HCl to give 1 mole of AgCl

The moles of AgCl formed  = 0.005 mole

Total volume of the solution = 50.0 ml + 50.0 ml = 100.0 ml

Now we have to calculate the mass of solution.

Mass of the solution = Density of the solution × Volume of the solution

Mass of the solution = 1.00 g/ml × 100.0 ml = 100 g

Now we have to calculate the heat.

q=m\times C\Delta T=m\times C \times (T_2-T_1)

where,

q = heat

C = specific heat capacity = 4.18J/g^oC

m = mass = 100 g

T_2 = final temperature = 24.21^oC

T_1 = initial temperature = 23.40^oC

Now put all the given values in the above expression, we get:

q=100g\times (4.18J/g^oC)\times (24.21-23.40)^oC

q=338.58J

Now  we have to calculate the enthalpy of the reaction.

\Delta H_{rxn}=\frac{q}{n}

where,

\Delta H_{rxn} = enthalpy of reaction = ?

q = heat of reaction = 338.58 J

n = moles of reaction = 0.005 mole

Now put all the given values in above expression, we get:

\Delta H_{rxn}=\frac{338.58J}{0.005mole}=6771.6J/mole=67.716KJ/mole

Conversion used : (1 KJ = 1000 J)

Therefore, the enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

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