Toluene is subjected to the action of the following reagents in the order given: (1) KMnO4,OH-, heat; then H3O (2) HNO3, H2SO4 (
1 answer:
Answer:
See image attached
Explanation:
The reaction of toluene with alkaline potassium permanganate in the presence of heat leads to the oxidation of the -CH3 to give benzoic acid.
Reaction benzoic acid with HNO3/H2SO4 yields the nitronium ion (NO2+).
Recall that -COOH is a metal director and deactivated the ring towards electrophilic substitution hence the m-nitrobenzoic acid is formed.
Reaction with FeBr3/Br2 yields the product shown in the image attached.
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Answer:
1.62
Explanation:
From the given information:
number of moles of benzamide
= 0.58 mole
The molality =
= 0.6837
Using the formula:
where;
dT = freezing point = 27
l = Van't Hoff factor = 1
kf = freezing constant of the solvent
∴
2.7 °C = 1 × kf × 0.6837 m
kf = 2.7 °C/ 0.6837m
kf = 3.949 °C/m
number of moles of NH4Cl =
= 1.316 mol
The molality =
= 1.5484
Thus;
the above kf value is used in determining the Van't Hoff factor for NH4Cl
i.e.
9.9 = l × 3.949 × 1.5484 m
l = 1.62