Iron should be in the 3d block
Answer:
Oxygen = 15.999 g/mol
Iron = 3 × 55.845 = 167.535 g/mol
CaCO3 = 20 × 100.0869 = 2001.738 g/mol
Kp= (COCl2)/[(CO)(Cl2)]= 1.49 x 10^8
1.49 x 10^8= (COCl2/((2.22x10-4)(2.22x10-4))
COCl2= 1.49x10^8 x ((2.22x10-4)(2.22x10-4))= 7.34 atm