To determine the k for the second condition, we use the Arrhenius equation which relates the rates of reaction at different temperatures. We do as follows:
ln k1/k2 = E / R (1/T2 - 1/T1) where E is the activation energy and R universal gas constant.
ln 1.80x10^-2 / k2 = 80000 / 8.314 ( 1/723.15 - 1/593.15)
k2 = 0.3325 L / mol-s
In a balloon there is a low pressure within the balloon. This means that the particles are more spaced out. Wheras in the cylinder they are under high pressure, meaning that the particles are much closer together!
The tractor trailer will push the car when they hit so therefore the car will have to greatest change
You kind of need to show more, but the independent variable would be something that you are changing to then measure the reaction, like the time left in for example.