Answer:
At 430.34 K the reaction will be at equilibrium, at T > 430.34 the
reaction will be spontaneous, and at T < 430.4K the reaction will not
occur spontaneously.
Explanation:
1) Variables:
G = Gibbs energy
H = enthalpy
S = entropy
2) Formula (definition)
G = H + TS
=> ΔG = ΔH - TΔS
3) conditions
ΔG < 0 => spontaneous reaction
ΔG = 0 => equilibrium
ΔG > 0 non espontaneous reaction
4) Assuming the data given correspond to ΔH and ΔS
ΔG = ΔH - T ΔS = 62.4 kJ/mol + T 0.145 kJ / mol * K
=> T = [ΔH - ΔG] / ΔS
ΔG = 0 => T = [ 62.4 kJ/mol - 0 ] / 0.145 kJ/mol*K = 430.34K
This is, at 430.34 K the reaction will be at equilibrium, at T > 430.34 the reaction will be spontaneous, and at T < 430.4K the reaction will not occur spontaneously.
Answer:
19.4 g of alum, will be its theoretical yield
Explanation:
The reaction is:
2 Al + 2 KOH + 4 H₂SO₄ + 22H₂O → 3H₂ + 2KAl(SO₄)₂•12H₂O
Let's determine the amount of acid.
M are the moles contained in 1 L of solution or it can be mmoles that are contained in 1 mL of solution
M = mmol /mL
M . mL = mmol
We replace: 8.3 mL . 9.9 M = 82.17 mmoles
We convert to moles: 82.17 mmol . 1 mol / 1000mmol = 0.082 moles
Ratio is 4:2
4 moles of sulfuric acid can make 2 moles of alum
By the way, 0.082 moles of acid may produce ( 0.082 . 2) /4 = 0.041085 moles.
We convert moles to mass:
Molar mass of alum is: 473.52 g/mol.
0.041085 moles . 473.52 g/mol = 19.4 g
Answer:
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