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shusha [124]
3 years ago
13

A negative ion is (larger/smaller) than its parent atom. Why?

Chemistry
1 answer:
Kay [80]3 years ago
5 0

Answer:

When an atom attracts extra electrons it becomes a negative ion. The negative ion is larger than the original atom. The positive nucleus remains the same, with the same attractive force. However, this attractive force is now pulling on more electrons and therefore has less effect.

Or

Positive ions are formed by removing one or more electrons from the outermost region of the atom. The opposite is true of negative ions. When electrons are added to form an anion, the increased electron-electron repulsions cause the electrons to spread out more in space. Thus, anions are larger than their parent atoms.

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A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc
Lorico [155]

Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

7 0
2 years ago
What happens to a line when the y-intercept is changed? Check all that apply.
tamaranim1 [39]

Answer:

As the y-intercept increases, the graph of the line shifts up;

As the y-intercept decreases, the graph of the line shifts down

Explanation:

There are two ways to think about this problem. The first way would be the graphical approach:

  • if we only change the y-intercept, this means we keep the same slope;
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Now, thinking algebraically, a line has the following equation in a general form:

y = mx + b

The y-intercept is essentially obtained when x = 0, then:

y = b:

  • if we increase b value, the y value increases, so the graph shifts upward;
  • if we decrease b value, the y value decreases, so the graph shifts downward.
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