1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
sveticcg [70]
2 years ago
8

A 45.0 mL solution of 0.0450 M hydroxylamine is extracted with 125 mL of solvent. The distribution constant for the reaction is

5.00 and the pKa of the protonated form of hydroxylamine is 5.960. Calculate the concentration of hydroxylamine remaining in the aqueous phase at pH=4.50 and pH=6.50 .
Chemistry
1 answer:
julia-pushkina [17]2 years ago
8 0

Answer:

pH = 4.5, concentration = 0.045 M.

pH = 6.5, concentration = 0.175 M.

Explanation:

The ka for the can be calculated by using the formula below;

Ka = 10^-pka = 10^-5.960 = 1.1 × 10^-6

The concentration of hydrogen ion at pH = 4.50 can be calculated as given below;

{H^+ } = 10^-4.50 = 3.2 × 10^-5 M.

(NB=> 10 in this regards means the inverse of log).

The next step is to determine the distribution coefficient which can be calculated by using the formula below;

distribution coefficient = (partition coefficient) × ka / ka + ( concentration of Hydrogen ion,H^+).

distribution coefficient =( 5 × 1.1 × 10^-6 ) / 1.1 × 10^-6 + 3.2 × 10^-5 M. = 5.5 × 10^-6/ 3.2 = 0.00000171875

The fraction remaining from the compound = 45.0 mL / 45.0 mL + (0.00000171875 × 125).

= 0.999995.

Thus, the concentration at pH = 4.5 = 0.999995 × 0.0450 M = 0.045 M

(B). pH=6.50, thus the concentration of Hydrogen ion = 10^-6.5 = 3.2 × 10^-7 M.

distribution coefficient = (partition coefficient) × ka / ka + ( concentration of Hydrogen ion,H^+).

distribution coefficient = (5 × 1.1 × 10^-6)/ 1.1 × 10^-6 + 3.2 × 10^-7 M).

distribution coefficient = 5.5 × 10^-6/ 1.42 × 10^-6 = 3.9.

Therefore, the concentration = 3.9 × 0.0450 M = 0.175 M.

You might be interested in
The dissociation of sulfurous acid (H2SO3) in aqueous solution occurs as follows:
aksik [14]

Answer:

The [SO₃²⁻]

Explanation:

From the first dissociation of sulfurous acid we have:

                         H₂SO₃(aq) ⇄ H⁺(aq) + HSO₃⁻(aq)

At equilibrium:  0.50M - x          x            x

The equilibrium constant (Ka₁) is:

K_{a1} = \frac{[H^{+}] [HSO_{3}^{-}]}{[H_{2}SO_{3}]} = \frac{x\cdot x}{0.5 - x} = \frac {x^{2}}{0.5 -x}

With Ka₁= 1.5x10⁻² and solving the quadratic equation, we get the following HSO₃⁻ and H⁺ concentrations:

[HSO_{3}^{-}] = [H^{+}] = 7.94 \cdot 10^{-2}M

Similarly, from the second dissociation of sulfurous acid we have:

                              HSO₃⁻(aq) ⇄ H⁺(aq) + SO₃²⁻(aq)

At equilibrium:  7.94x10⁻²M - x          x            x

The equilibrium constant (Ka₂) is:  

K_{a2} = \frac{[H^{+}] [SO_{3}^{2-}]}{[HSO_{3}^{-}]} = \frac{x^{2}}{7.94 \cdot 10^{-2} - x}  

Using Ka₂= 6.3x10⁻⁸ and solving the quadratic equation, we get the following SO₃⁻ and H⁺ concentrations:

[SO_{3}^{2-}] = [H^{+}] = 7.07 \cdot 10^{-5}M

Therefore, the final concentrations are:

[H₂SO₃] = 0.5M - 7.94x10⁻²M = 0.42M

[HSO₃⁻] = 7.94x10⁻²M - 7.07x10⁻⁵M = 7.93x10⁻²M

[SO₃²⁻] = 7.07x10⁻⁵M

[H⁺] = 7.94x10⁻²M + 7.07x10⁻⁵M = 7.95x10⁻²M

So, the lowest concentration at equilibrium is [SO₃²⁻] = 7.07x10⁻⁵M.

I hope it helps you!

8 0
2 years ago
Which describes why liquid moves through a straw?
vodomira [7]

Answer:

C.

The air pressure creates a vacuum in the straw that pulls the air into the liquid.

4 0
2 years ago
How is the mass number related to the number of protons and neutrons an atom has
matrenka [14]
Mass is equal to protons plus neutrons
To find the protons its the atomic number
8 0
3 years ago
Which directly contribute to sea level rise?(1 point) It's actually earth science.
Rudiy27

Answer:?Any one have the answers?

Explanation:d

8 0
2 years ago
Read 2 more answers
Not sure how to answer this:
ahrayia [7]

Answer:

A. The red side is acidic.

B. Because it has more positive hydrogen ions.

C. The blue side is basic.

D. Because it has more negative hydroxide ion.

4 0
3 years ago
Other questions:
  • Is it possible for the properties of a substance with a specific type of bond to vary
    8·1 answer
  • [Standard Enthalpy of Formation]
    13·2 answers
  • If you are administering an oral acetaminophen dose of 400. mg from a bottle at a concentration of 32.0 mg/mL , how many millili
    10·1 answer
  • The heat energy required to change a unit mass of a solid into a liquid at constant temperature is called
    6·2 answers
  • Is hydrogen dioxide (water) always produced when an acidic solution is mixed with a basic solution?
    8·2 answers
  • What is an ion?a) an atom that has either gained or lost electron(s)b) an atom that is sharing electrons with another atomc) an
    8·1 answer
  • summer school is over, and I'm feeling self-destructive. Take all of my points and have a good night. 3/3
    6·2 answers
  • Please help me with 6 7 8 and don’t send me a link tell me here please
    11·1 answer
  • What pressure will be exerted by 15 g of Co, at 25°C and a volume of 610. ml?
    14·1 answer
  • What is electromagnetic radiation?
    11·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!