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Leona [35]
3 years ago
9

Be sure to answer all parts. Show the overall reaction for formation of racemic 3−bromohexane from (E)−3−hexene by enterin

g the structures of the products and reactants in the template provided. Part 1 out of 3 draw structure ... arr draw structure ... + draw structure ... (E)−3−hexene (S)−3−bromohexane (R)−3−bromohexane Racemic product = 50% (S) and 50% (R)
Chemistry
1 answer:
Viktor [21]3 years ago
8 0

Answer:

See explanation

Explanation:

The mechanism for the formation of bromohexane from hexene has been clearly shown in the image attached to this answer.

Hexene is attacked by HBr and a carbocation is first formed as shown. The carbocation is flat and planar. it can be attacked on either face by the bromide ion.

Attack on either faces yields a racemic mixture of the R and S enantiomer as shown in the image.

You can use the mechanism shown to fill in the structures.

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Calculate ΔGrxn at 298 K under the conditions shown below for the following reaction.
algol13

Answer : The value of \Delta G_{rxn} is -24.9 kJ/mol

Explanation :

First we have to calculate the value of 'Q'.

The given balanced chemical reaction is,

Fe_2O_3(s)+3CO(g)\rightarrow 2Fe(s)+3CO_2(g)

The expression for reaction quotient will be :

Q=\frac{(p_{CO_2})^3}{(p_{CO})^3}

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

Q=\frac{(2.1)^3}{(1.4)^2}

Q=3.375

Now we have to calculate the value of \Delta G_{rxn}.

The formula used for \Delta G_{rxn} is:

\Delta G_{rxn}=\Delta G^o+RT\ln Q    ............(1)

where,

\Delta G_{rxn} = Gibbs free energy for the reaction  = ?

\Delta G_^o =  standard Gibbs free energy  = -28.0 kJ/mol

R = gas constant = 8.314\times 10^{-3}kJ/mole.K

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Q = reaction quotient = 3.375

Now put all the given values in the above formula 1, we get:

\Delta G_{rxn}=(-28.0kJ/mol)+[(8.314\times 10^{-3}kJ/mole.K)\times (298K)\times \ln (3.375)

\Delta G_{rxn}=-24.9kJ/mol

Therefore, the value of \Delta G_{rxn} is -24.9 kJ/mol

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