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miss Akunina [59]
3 years ago
11

Assign priorities in the following set of substituents according to Cahn-Ingold-Prelog rules.

Chemistry
1 answer:
LuckyWell [14K]3 years ago
7 0

Answer:

Assign priorities in the following set of substituents according to Cahn-Ingold-Prelog rules.

-OCH3 -Br -Cl -CH2OH

Explanation:

To give priorities for the substituents that are attached to chiral carbon and  to assign either R or S-configuration the following rules were proposed:

1. The atom with the highest atomic number is given first priority.

2. If the Groups attached to chiral carbon are having the same first atom, then check for the atomic number of the second atom.

Among the given groups,

-Br has the highest atomic number, so it is given first priority.

Then, -Cl.

Then, -OCH3

and the last one is -CH2OH.

Hence, the order is :

BCAD.

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determine the frequency and wavelength (in nm) of the light emitted when the e- fell from n=4 and n=2
Lostsunrise [7]

Answer:

Frequency = 6.16 ×10¹⁴ Hz

λ = 4.87×10² nm

Explanation:

In case of hydrogen atom energy associated with nth state is,

En =  -13.6/n²

For n = 2

E₂ = -13.6 / 2²

E₂ = -13.6/4

E₂ = -3.4 ev

Kinetic energy of electron = -E₂ = 3.4 ev

For n = 4

E₄ = -13.6 / 4²

E₄ = -13.6/16

E₄ = -0.85 ev

Kinetic energy of electron = -E₄ = 0.85 ev

Wavelength of radiation emitted:

E = hc/λ = E₄ - E₂

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by putting values,

6.63×10⁻³⁴Js × 3×10⁸m/s / λ = -0.85ev   - (-3.4ev )

6.63×10⁻³⁴ Js× 3×10⁸m/s / λ = 2.55 ev

λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s  /2.55ev

λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s  /2.55× 1.6×10⁻¹⁹ J

λ = 19.89 ×10⁻²⁶ Jm / 2.55× 1.6×10⁻¹⁹ J

λ = 19.89 ×10⁻²⁶ Jm / 4.08×10⁻¹⁹ J

λ = 4.87×10⁻⁷ m

m to nm:

4.87×10⁻⁷ m ×10⁹nm/1 m

4.87×10² nm

Frequency:

Frequency = speed of electron / wavelength

by putting values,

Frequency = 3×10⁸m/s /4.87×10⁻⁷ m

Frequency = 6.16 ×10¹⁴ s⁻¹

s⁻¹ = Hz

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3 0
3 years ago
The combustion of ethene in the presence of excess oxygen yields carbon dioxide and water: c2h4 (g) + 3o2 (g) → 2co2 (g) + 2h2o
meriva

Answer:

\boxed{-267.5}

Explanation:

You can calculate the entropy change of a reaction by using the standard molar entropies of reactants and products.

The formula is

\Delta_{r} S^{\circ} = \sum_n {nS_{\text{products}}^{\circ} - \sum_{m} {mS_{\text{reactants}}^{\circ}}}

The equation for the reaction is

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\Delta_{r} S^{\circ} = (2\times213.6 + 2\times69.9) - (1\times219.5 + 3\times205.0)\\\\= 567.0 - 834.5 = \boxed{-267.5 \text{ J}\cdot\text{K}^{-1} \text{mol}^{-1}}

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