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g100num [7]
3 years ago
5

Based on the standard EMF series and your knowledge of half-reactions, determine the cell potential and spontanei ty of a cell t

hat consists of a pure cobalt electrode in a solution of Co^2+ ions; the other half is a lead electrode immersed in a Pb^2+ solution.
Pb +2e- Pb Sn +2e Sn Ni 2e Ni Co 2e -0.126 -0.136 -0.250 -0.277 Co
a. +0.403, spontaneous
b. -0.403, nonspontaneous
c. +0.151, spontaneous
d. -0.151, nonspontaneous
Chemistry
1 answer:
Taya2010 [7]3 years ago
8 0

Answer:

+0.151, spontaneous

Explanation:

Given that;

Co^2+(aq) + 2e ---->Co(s) -0.28 V

Pb^2+(aq) + 2e ---->Pb(s). -0.13 V

Hence Co is the anode and Pb is the cathode

E°cell = E°cathode - E°anode

So;

E°cell = -0.13 V - (-0.28 V)

E°cell = 0.15 V

The cell reaction is spontaneous since E°cell is positive.

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A sample of 1.000 g of a compound containing carbon and hydrogen reacts with oxygen at elevated temperature to yield 0.692 g H₂O
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Answer :

(a) 1.000 g of compound containing carbon and hydrogen is, 0.922 g and 0.0769 g respectively.

(b) There is no other element present in the compound.

Explanation :

(a) Now we have to determine the masses of C and H in the sample.

The chemical equation for the combustion of hydrocarbon having carbon, hydrogen and oxygen follows:

C_xH_y+O_2\rightarrow CO_2+H_2O

where, 'x' and 'y' are the subscripts of Carbon and hydrogen respectively.

We are given:

Mass of CO_2=3.381g

Mass of H_2O=0.692g

We know that:

Molar mass of carbon dioxide = 44 g/mol

Molar mass of water = 18 g/mol

For calculating the mass of carbon:

In 44 g of carbon dioxide, 12 g of carbon is contained.

So, in 3.381 g of carbon dioxide, \frac{12}{44}\times 3.381=0.922g of carbon will be contained.

For calculating the mass of hydrogen:

In 18 g of water, 2 g of hydrogen is contained.

So, in 0.692 g of water, \frac{2}{18}\times 0.692=0.0769g of hydrogen will be contained.

Thus, 1.000 g of compound containing carbon and hydrogen is, 0.922 g and 0.0769 g respectively.

(b) Now we have to determine the compound contain any other elements or not.

Mass carbon + Mass of hydrogen = 0.922 g + 0.0769 g = 0.999 g ≈ 1 g

This means that there is no other element present in the compound.

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