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andrew11 [14]
3 years ago
6

While following the Dumas method, a student assumes that the contents of the container are the same temperature as the water bat

h. If this is NOT true, and the material in the container is cooler, how will this influence the calculations?
A. The calculated Molar Mass will be smaller.

B. The calculated Molar Mass will not be affected.

C. The calculated Molar Mass will be larger.
Chemistry
1 answer:
Nataliya [291]3 years ago
5 0

Answer:

A

Explanation:

the Molar mass will be smaller as the content of the container is not directly proportional to the temperature of the water bath.

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Answer:

The experimental value of ΔH is -50 kJ/mol

Explanation:

<u>Step 1: </u>Data given

Volume of 1.0 M NaOH = 10.0 mL = 0.01 L

Volume of 1.0 M HCl = 10.0 mL = 0.01 L

Temperature before mixing = 20 °C

Final temperature = 26 °C

Specific heat of solution = 4.2 J/g°C

Density = 1g/mL

<u>Step 2: </u>Calculate q

q = m*c*ΔT

⇒ with m = the mass

  ⇒ 20.0 mL * 1g/mL = 20 grams

⇒  c = specific heat of solution = 4.2 J/g°C

⇒ ΔT = T2 -T1 = 26 -20 = 6 °C

q = 20g * 4.2 J/g°C * 6°C

q = 504 J

ΔHrxn = -q  ( because it's an exothermic reaction)

ΔHrxn = -504 J

<u>Step 3:</u> Calculate number of moles

Moles = Molarity * volume

Moles = 1M *0.01 L = 0.01 moles

<u>Step 4:</u> Calculate the experimental value of ΔH

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Answer:

5 g of H₂ are contained in the vessel

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We determine molar mass of H₂.

This is a dyatomic molecule, as molar mass of H is 1g/mol, molar mass of H₂ will be 2g/mol.

Let's make the conversion of units:

2.5 mol . 2g/mol = 5 g

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The properties of an ideal gas are explained by the kinetic-molecular theory. An ideal gas assumes there is no intermolecular attraction between the molecules. High pressure would make the particles closer together and interact more, going against the kinetic molecular theory that states there are large spaces between particles and no interactions between particles. Low temperature would make the particles slow which prevents them from overcoming the intermolecular attraction between particles.

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