Answer and Explanation:
For the following balanced reaction:
PCl₅(g) ↔ PCl₃(g) + Cl₂(g)
We can see that all reactants and products are gases, so it is an homogeneous equilibrium. The expression for the equilibrium constant Kp can be written from the partial pressures (P) of reactants and products as follows:
Where PPCl₃ is the partial pressure of PCl₃ (reactant), PCl₂ is the partial pressure of Cl₂ (reactant) and PPCl₅ is the partial pressure of PCl₅ (product).
The Reaction is spontaneous when temperature is 430 K. Hence, Option (C) is correct.
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What is Spontaneous reaction ?</h3>
Reactions are favorable when they result in a decrease in enthalpy and an increase in entropy of the system.
When both of these conditions are met, the reaction occurs naturally.
Spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring.
According to Gibb's equation:
ΔG = ΔH - TΔS
ΔG = Gibbs free energy
ΔH = enthalpy change = +62.4 kJ/mol
ΔS = entropy change = +0.145 kJ/molK
T = temperature in Kelvin
- ΔG = +ve, reaction is non spontaneous
- ΔG = -ve, reaction is spontaneous
- ΔG = 0, reaction is in equilibrium
ΔH - TΔS = 0 for reaction to be spontaneous
T = ΔH / ΔS
Here,
T = 500K
Thus the Reaction is spontaneous when temperature is 500 K.
Learn more about Gibbs free energy here ;
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The most concentrated solution is b
The frequency stays the same it just gets louder
Potassium hypochlorite when dissolved in water would dissociate into ions namely the potassium ions and the hypochlorite ions. Furthermore, hypochlorite ions would interact with water molecules and would decompose further. The dissociation reactions are as follows:
KClO <=> K+ + ClO-
ClO- + H2O <=> HOCl + OH-
Adding the two reactions, would give
KClO + ClO- + H2O = K+ + HOCl + OH- + ClO-
The two ClO- ions in both sides would cancel giving us the net ionic equation:
KClO + H2O = K+ + HOCl + OH-
