Covalent for the first one
Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
Answer:
3224 kJ/mol
Explanation:
The combustion of benzoic acid occurs as follows:
C₇H₆O₂ + 13/2O₂ → 7CO₂ + 3H₂O + dE
The change in temperature in the reaction is the change due the energy released, that is:
3.256K * (10.134kJ / K) = 33.00kJ are released when 1.250g reacts
To find the heat released per mole we have to find the moles of benzoic acid:
<em>Moles benzoic acid -Molar mass: 122.12g/mol-:</em>
1.250g * (1mol / 122.12g) = 0.0102 moles
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The dE combustion per mole of benzoic acid is:
33.00kJ / 0.0102moles =
<em>3224 kJ/mol </em>
I believe the answer is 0.016. if i am wrong please tell me if it's wrong. the second option
