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V125BC [204]
3 years ago
8

Find [H+] of a 0.056 M hydrofluoric acid solution. Ka = 1.45 x 10-7

Chemistry
1 answer:
brilliants [131]3 years ago
8 0

Answer:  [H^+] of 0.056 M HF solution is 8.96\times 10^{-5}

Explanation:

HF\rightarrow H^+F^-

 cM              0             0

c-c\alpha        c\alpha          c\alpha  

So dissociation constant will be:

K_a=\frac{(c\alpha)^{2}}{c-c\alpha}

Give c= 0.056 M and \alpha = ?

K_a=1.45\times 10^{-7}

Putting in the values we get:

1.45\times 10^{-7}=\frac{(0.056\times \alpha)^2}{(0.056-0.056\times \alpha)}

(\alpha)=0.0016

[H^+]=c\times \alpha

[H^+]=0.056\times 0.0016=8.96\times 10^{-5}  

Thus [H^+] of 0.056 M HF solution is 8.96\times 10^{-5}

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Calculate the change in the entropy of the system and also the change in the entropy of the surroundings, and the resulting tota
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Answer:

(a) ΔS_{sys}  = 2.881 J/K; ΔS_{sur}  = -2.881 J/K; total change in entropy = 0

(b)ΔS_{sys}  = 2.881 J/K; ΔS_{sur}  = 0 ; total change in entropy = 2.881 J/K

(c) ΔS_{sys}  = 0 ; ΔS_{sur}  = 0 ; total change in entropy = 0

Explanation:

In the given problem, we need to calculate the change in the entropy of the system and also the change in the entropy of the surroundings, and the resulting total change in entropy, when a sample of nitrogen gas of mass 14 g at 298 K and 1.00 bar doubles its volume. We have the following variable:

mass (m) = 14 g

Temperature = 298 K

Pressure = 1.00 bar

Initial volume = V_{1}

Final volume = V_{2} = 2V_{1}

(a) Change in entropy of the system ΔS_{sys} = nRIn\frac{V_{2} }{V_{1} }

where R = 8.314 J/(mol*K)

n = number of moles = mass/molar mass = 14/ 28 = 0.5 moles

ΔS_{sys} = 0.5*8.314*ln2 = 2.881 J/K

Change in entropy of the surrounding ΔS_{sur} = -2.881 J/K

Therefore, for a reversible process, the total change in entropy = ΔS_{sys}+ΔS_{sur} = 2.881 - 2.881 = 0

(b) Because entropy is a state function, we use the same procedure as in part (a). Thus, ΔS_{sys}  = 2.881 J/K

Since surrounding does not change in this process ΔS_{sur} = 0.

total change in entropy = ΔS_{sys}+ΔS_{sur} = 2.881 - 0 = 2.88 J/K

(c) For an adiabatic reversible expansion, q(rev) = 0, thus:

ΔS_{sys}  = 0

Since heat energy is not transferred from the system to the surrounding

ΔS_{sur}  = 0

total change in entropy = ΔS_{sys}+ΔS_{sur} = 0

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2 years ago
The pressure on a sample of gas is increased from 1.0 atm to 3.0 atm. If the new volume is 0.52 L, find the original volume.
swat32

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