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2 years ago

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If the experiment were repeated using a cuvettes with a path length of 2.0 cm, how would that affect the absorbance values for t

he Co2 solutions (if at all), assuming all of the concentrations remained unchanged?

1 answer:

inessss [21]2 years ago

5 0

Answer:

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The dissociation of sulfurous acid (H2SO3) in aqueous solution occurs as follows:

aksik [14]

Answer:

The [SO₃²⁻]

Explanation:

From the first dissociation of sulfurous acid we have:

H₂SO₃(aq) ⇄ H⁺(aq) + HSO₃⁻(aq)

At equilibrium: 0.50M - x x x

The equilibrium constant (Ka₁) is:

$K_{a1} = \frac{[H^{+}] [HSO_{3}^{-}]}{[H_{2}SO_{3}]} = \frac{x\cdot x}{0.5 - x} = \frac {x^{2}}{0.5 -x}$

With Ka₁= 1.5x10⁻² and solving the quadratic equation, we get the following HSO₃⁻ and H⁺ concentrations:

$[HSO_{3}^{-}] = [H^{+}] = 7.94 \cdot 10^{-2}M$

Similarly, from the second dissociation of sulfurous acid we have:

HSO₃⁻(aq) ⇄ H⁺(aq) + SO₃²⁻(aq)

At equilibrium: 7.94x10⁻²M - x x x

The equilibrium constant (Ka₂) is:

$K_{a2} = \frac{[H^{+}] [SO_{3}^{2-}]}{[HSO_{3}^{-}]} = \frac{x^{2}}{7.94 \cdot 10^{-2} - x}$

Using Ka₂= 6.3x10⁻⁸ and solving the quadratic equation, we get the following SO₃⁻ and H⁺ concentrations:

$[SO_{3}^{2-}] = [H^{+}] = 7.07 \cdot 10^{-5}M$

Therefore, the final concentrations are:

[H₂SO₃] = 0.5M - 7.94x10⁻²M = 0.42M

[HSO₃⁻] = 7.94x10⁻²M - 7.07x10⁻⁵M = 7.93x10⁻²M

[SO₃²⁻] = 7.07x10⁻⁵M

[H⁺] = 7.94x10⁻²M + 7.07x10⁻⁵M = 7.95x10⁻²M

So, the lowest concentration at equilibrium is [SO₃²⁻] = 7.07x10⁻⁵M.

I hope it helps you!

8 0

3 years ago

Which of these solution is most basic

pantera1 [17]

Answer:

There is nothing to answer lol

8 0

2 years ago

Read 2 more answers

What must be the molarity of an aqueous solution of trimethylamine, (ch3)3n, if it has a ph = 11.20? (ch3)3n+h2o⇌(ch3)3nh++oh−kb

Stolb23 [73]

0.040 mol / dm³. (2 sig. fig.)

<h3>Explanation</h3>

$(\text{CH}_3)_3\text{N}$ in this question acts as a weak base. As seen in the equation in the question, $(\text{CH}_3)_3\text{N}$ produces $\text{OH}^{-}$ rather than $\text{H}^{+}$ when it dissolves in water. The concentration of $\text{OH}^{-}$ will likely be more useful than that of $\text{H}^{+}$ for the calculations here.

Finding the value of $[\text{OH}^{-}]$ from pH:

Assume that $\text{pK}_w = 14$ ,

$\begin{array}{ll}\text{pOH} = \text{pK}_w - \text{pH} \\ \phantom{\text{pOH}} = 14 - 11.20 &\text{True only under room temperature where }\text{pK}_w = 14 \\\phantom{\text{pOH}}= 2.80\end{array}$ .

$[\text{OH}^{-}] =10^{-\text{pOH}} =10^{-2.80} = 1.59\;\text{mol}\cdot\text{dm}^{-3}$ .

Solve for $[(\text{CH}_3)_3\text{N}]_\text{initial}$ :

$\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\text{equilibrium}} = \text{K}_b = 1.58\times 10^{-3}$

Note that water isn't part of this expression.

The value of Kb is quite small. The change in $(\text{CH}_3)_3\text{N}$ is nearly negligible once it dissolves. In other words,

$[(\text{CH}_3)_3\text{N}]_\text{initial} = [(\text{CH}_3)_3\text{N}]_\text{final}$ .

Also, for each mole of $\text{OH}^{-}$ produced, one mole of $(\text{CH}_3)_3\text{NH}^{+}$ was also produced. The solution started with a small amount of either species. As a result,

$[(\text{CH}_3)_3\text{NH}^{+}] = [\text{OH}^{-}] = 10^{-2.80} = 1.58\times 10^{-3}\;\text{mol}\cdot\text{dm}^{-3}$ .

$\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{[(\text{CH}_3)_3\text{N}]_\textbf{initial}} = \text{K}_b = 1.58\times 10^{-3}$ ,

$[(\text{CH}_3)_3\text{N}]_\textbf{initial} =\dfrac{[\text{OH}^{-}]_\text{equilibrium}\cdot[(\text{CH}_3)_3\text{NH}^{+}]_\text{equilibrium}}{\text{K}_b}$ ,

$[(\text{CH}_3)_3\text{N}]_\text{initial} =\dfrac{(1.58\times10^{-3})^{2}}{6.3\times10^{-5}} = 0.040\;\text{mol}\cdot\text{dm}^{-3}$ .

8 0

3 years ago

The amount of dissolved salt in water is know as

Aleksandr [31]

Answer:

The water is solvent and the salt is solute

5 0

3 years ago

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Which statement is true about metals and metalloids? A. All metals and metalloids have luster. B. Metals are good conductors and

Aleks [24]

I believe the statement that is true of metals and metalloids is B. Metals are good conductors and metalloids are bad conductors.

7 0

3 years ago

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