Answer : The correct option is, (b) 22.5 M
Explanation : Given,
Mass of calcium nitrate tetrahydrate = 266 g
Molar mass of calcium nitrate tetrahydrate = 236.15 g/mole
Volume of solution = 
Molarity : It is defined as the moles of solute present in one liter of solution.
Formula used :

Now put all the given values in this formula, we get:

As calcium nitrate tetrahydrate dissociate to give 1 mole of calcium ion, 2 moles of nitrate ion and 4 moles of water.
The concentration of nitrate ion = 
Thus, the concentration of nitrate ion is, 22.5 M
Do not ionize in solutions
Poor conductors of electricity/heat
Low melting/boiling points
gases or liquids at room temperature
Mass of KCl= 1.08 g
<h3>Further explanation</h3>
Given
1 g of K₂CO₃
Required
Mass of KCl
Solution
Reaction
K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂
mol of K₂CO₃(MW=138 g/mol) :
= 1 g : 138 g/mol
= 0.00725
From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :
= 2/1 x mol K₂CO₃
= 2/1 x 0.00725
= 0.0145
Mass of KCl(MW=74.5 g/mol) :
= mol x MW
= 0.0145 x 74.5
= 1.08 g