25 °C = ________ K which one 298 0 33 197

The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed

Oksanka [162]

Answer:

(a) The rate of disappearance of $O_{2}$ is: $4.65*10^{-5}$ M/s

(b) The value of rate constant is: 0.83036 $M^{-2}s^{-1}$

(c) The units of rate constant is: $M^{-2}s^{-1}$

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

$2NO(g)+O_{2}->2NO_{2}$

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = $-\frac{d}{dt}[O_{2}]$ = $\frac{1}{2}\frac{d}{dt}[NO_{2}]$ -----(1)

According to the question, the reaction is second order in NO and first order in $O_{2}$ .

Then we can say that, rate = k $[NO]^{2}[O_{2}]$ -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

$-\frac{d}{dt}[NO]$ = $9.3*10^{-5}$ M/s.

(a) From (1), we can get the rate of disappearance of $O_{2}$ .

Rate of disappearance of $O_{2}$ = $-\frac{d}{dt}[O_{2}]$ = (0.5)*( $9.3*10^{-5}$ ) M/s = $4.65*10^{-5}$ M/s.

(b) The rate of the reaction can be obtained from (1).

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = (0.5)*( $9.3*10^{-5}$ )

rate = $4.65*10^{-5}$ M/s

The value of rate constant can be obtained by using (2).

rate constant = k = $\frac{rate}{[NO]^{2}[O_{2}]}$

k = $\frac{4.65*10^{-5}}{(0.040)^{2}(0.035)}$ = 0.83036 $M^{-2}s^{-1}$

(c) The units of the rate constant can be obtained from (2).

k = $\frac{rate}{[NO]^{2}[O_{2}]}$

Substituting the units of rate as M/s and concentrations as M, we get:

$\frac{Ms^{-1} }{M^{3}}$ = $M^{-2}s^{-1}$

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

$rate\alpha [NO]^{2}$

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of $(1.8)^{2}$ = 3.24

5 0

3 years ago

Word Bank: automobiles, fossil fuels, plastic packaging, planes, trains _________________________ requires oil to create it.

Ymorist [56]

Plastic packaging requires oil to create it

7 0

3 years ago

Write a scientific report on the clouds seeding using condensation nuclei and showing its relationship to saturated solutions.

Andrej [43]

Answer:

um thats tricky man

Explanation:

i dont even know what nuclei is

6 0

3 years ago

Problems associated with a declining population size include _____.

Rzqust [24]

The correct answer is weakened economic strength. When a declning population size starts to occur and develop, the country may experience a weakened economic strength, since the power to produce and create products and services has been hindered and weakened due to its declining population.

7 0

3 years ago

Read 2 more answers

What is the relationship between the internal energy of a substance and its particle movement?

ss7ja [257]

Answer: The closeness, arrangement and motion of the particles in a substance change when it changes state. Materials are a store of internal energy , due to the motion of particles and the chemical bonds between them. When a substance is heated, its internal energy increases: the movement of its particles increases.

Explanation:

6 0

3 years ago