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Stells [14]
3 years ago
5

Compound C with molar mass 205gmol-1 , contains 3.758g of carbon , 0.316g of hydrogen and 1.251g of oxygen. Determine the molecu

lar formula.
Chemistry
1 answer:
labwork [276]3 years ago
8 0

Answer:

Molecular formula => C₁₂H₁₂O₃

Explanation:

From the question given above, the following data were obtained:

Molar mass of compound = 205gmol¯¹

Mass of Carbon (C) = 3.758 g

Mass of Hydrogen (H) = 0.316 g

Mass of Oxygen (O) = 1.251 g

Molecular formula =?

We'll begin by determining the empirical formula of the compound. This can be obtained as follow:

C = 3.758 g

H = 0.316 g

O = 1.251 g

Divide by their molar masses

C = 3.758 /12 = 0.313

H = 0.316 /1 = 0.316

O = 1.251 /16 = 0.078

Divide by the smallest.

C = 0.313 / 0.078 = 4

H = 0.316 / 0.078 = 4

O = 0.078 / 0.078 = 1

Thus, the empirical formula of the compound is C₄H₄O

Finally, we shall determine the molecular formula of the compound. This can be obtained as follow:

Molar mass of compound = 205gmol¯¹

Empirical formula => C₄H₄O

Molecular formula =>?

[C₄H₄O]ₙ = 205

[(12×4) + (4×1) +16]n = 205

[48 + 4 +16]n = 205

68n = 205

Divide both side by n

n = 205 / 68

n = 3

Molecular formula => [C₄H₄O]ₙ

Molecular formula => [C₄H₄O]₃

Molecular formula => C₁₂H₁₂O₃

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Determine the [OH−] of a solution that is 0.115 M in CO32−. For carbonic acid (H2CO3), Ka1=4.3×10−7 and Ka2=5.6×10−11.
lianna [129]

Answer:

[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.

Explanation:

Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.

Analysis:

            H₂CO₃(aq)     ⇄     H⁺(aq)    +    HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷

C(i)          0.115M                      0                  0

ΔC              -x                        +x                  +x

C(eq)    0.115M - x                   x                    x

            ≅ 0.115M

Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M

= 4.3 x 10⁻⁷  => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.

In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion  concentration, the hydroxide ion concentration is then calculated from

[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.

________________________________________________________

NOTE: The 2.32 x 10⁻⁴M  value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.

4 0
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