Answer:
a)W=12.62 kJ/mol
b)W=12.59 kJ/mol
Explanation:
At T = 100 °C the second and third virial coefficients are
B = -242.5 cm^3 mol^-1
C = 25200 cm^6 mo1^-2
Now according isothermal work of one mole methyl gas is
W=-
a=
b=
from virial equation

And

a=
b=
Now calculate V1 and V2 at given condition

Substitute given values
= 1 x 10^5 , T = 373.15 and given values of coefficients we get

Solve for V1 by iterative or alternative cubic equation solver we get

Similarly solve for state 2 at P2 = 50 bar we get

Now

a=241.33
b=30780
After performing integration we get work done on the system is
W=12.62 kJ/mol
(b) for Z = 1 + B' P +C' P^2 = PV/RT by performing differential we get
dV=RT(-1/p^2+0+C')dP
Hence work done on the system is

a=
b=
by substituting given limit and P = 1 bar , P2 = 50 bar and T = 373 K we get work
W=12.59 kJ/mol
The work by differ between a and b because the conversion of constant of virial coefficients are valid only for infinite series
Answer:
A certain vehicle loses 3.5% of its value each year. If the vehicle has an initial value of $11,168, construct a model that represents the value of the vehicle after a certain number of years. Use your model to compute the value of the vehicle at the end of 6 years.
Explanation:
Answer:
Ponding will occur in 40mins
Explanation:
We say that the infiltration rate is the velocity or speed at which water enters into the soil. This often times is measured by the depth (in mm) of the water layer that can enter the soil in one hour. An infiltration rate of 15 mm/hour means that a water layer of 15 mm on the soil surface, will take one hour to infiltrate.
Consider checking attachment for the step by step solution.
Answer:
98°C
Explanation:
Total surface area of cylindrical fin = πr² + 2πrl , r = 0.015m; l= 0.1m; π =22/7
22/7*(0.015)² + 22/7*0.015*0.1 = 7.07 X 10∧-4 + 47.1 X 10∧-4 = (54.17 X 10∧-4)m²
Temperature change, t = (50 - 25)°C = 25°C = 298K
Hence, Temperature = 150 X (54.17 X 10∧-4) X 298/123 = 242.14/124 = 2.00K =
∴ Temperature change = 2.00K
But temperature, T= (373 - 2)K = 371 K
In °C = (371 - 273)K = 98°C