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ANEK [815]
2 years ago
15

A city continuously disposes of effluent from a wastewater treatment plant into a river. The minimum flow in the river is 130 m3

/s, and the discharge from the treatment plant is 37 m3/s. Upstream from the outfall, the background concentration is 0.69 mg/L. The maximum allowable concentration in the river is 1.1 mg/L. What is the maximum concentration that of the pollutant (in mg/L) that can be safely discharged from the wastewater treatment plant
Chemistry
1 answer:
Vera_Pavlovna [14]2 years ago
6 0

Answer:

2.54\ \text{mg/L}

Explanation:

C = Allowable concentration = 1.1 mg/L

Q_1 = Flow rate of river = 130\ \text{m}^/\text{s}

Q_2 = Discharge from plant = 37\ \text{m}^3/\text{s}

C_1 = Background concentration = 0.69 mg/L

C_2 = Maximum concentration that of the pollutant

The concentration of the mixture will be

C=\dfrac{Q_1C_1+Q_2C_2}{Q_1+Q_2}\\\Rightarrow C_2=\dfrac{C(Q_1+Q_2)-Q_1C_1}{Q_2}\\\Rightarrow C_2=\dfrac{1.1(130+37)-130\times 0.69}{37}\\\Rightarrow C_2=2.54\ \text{mg/L}

The maximum concentration that of the pollutant (in mg/L) that can be safely discharged from the wastewater treatment plant is 2.54\ \text{mg/L}.

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If a system has a reaction quotient of 2.13 ✕ 10−15 at 100°C, what will happen to the concentrations of COBr2, CO, and Br2 as th
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This is an incomplete question, here is a complete question.

Consider the following equilibrium at 100°C.

COBr_2(g)\rightleftharpoons CO(g)+Br_2(g)

K_c=4.74\times 10^4

Concentration at equilibrium:

[COBr_2]=1.58\times 10^{-6}M

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If a system has a reaction quotient of 2.13 × 10⁻¹⁵ at 100°c, what will happen to the concentrations of COBr₂, Co and Br₂ as the reaction proceeds to equilibrium?

Answer : The concentrations of Co and Br₂ decreases and the concentrations of COBr₂ increases.

Explanation :

Reaction quotient (Q) : It is defined as the measurement of the relative amounts of products and reactants present during a reaction at a particular time.

The given balanced chemical reaction is,

COBr_2(g)\rightleftharpoons CO(g)+Br_2(g)

The expression for reaction quotient will be :

Q=\frac{[CO][Br_2]}{[COBr_2]}

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

Q=\frac{(2.78\times 10^{-3})\times (2.51\times 10^{-5})}{(1.58\times 10^{-6})}=4.42\times 10^{-2}

The given equilibrium constant value is, K_c=4.74\times 10^4

Equilibrium constant : It is defined as the equilibrium constant. It is defined as the ratio of concentration of products to the concentration of reactants.

There are 3 conditions:

When Q>K_c that means product > reactant. So, the reaction is reactant favored.

When Q that means reactant > product. So, the reaction is product favored.

When Q=K_c that means product = reactant. So, the reaction is in equilibrium.

From the above we conclude that, the Q that means product < reactant. So, the reaction is product favored that means reaction must shift to the product (right) to be in equilibrium.

Hence, the concentrations of Co and Br₂ decreases and the concentrations of COBr₂ increases.

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