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Answer:
Explanation:
Entropy is the measure of randomness or disorder of a system.
A system has positive value of entropy if the disorder increases and a system has negative value of entropy if the disorder decreases.
1.
As 4 moles of gaseous reactants are changing to 2 moles of gaseous products, the randomness is decreasing and the entropy is negative
2.
As 9 moles of gaseous reactants are changing to 10 moles of gaseous products, the randomness is increasing and the entropy is positive.
3.
As 1 mole of solid reactants is changing to 2 moles of gaseous products, the randomness is increasing and the entropy is positive.
4.
As 4 moles of gaseous reactants is changing to 5 moles of gaseous products, the randomness is increasing and the entropy is positive
5.
As 4 moles of gaseous reactants is changing to 1 moles of gaseous products, the randomness is decreasing and the entropy is negative.
Answer:
the Molar heat of Combustion of diphenylacetylene =
Explanation:
Given that:
mass of diphenylacetylene = 0.5297 g
Molar Mass of diphenylacetylene = 178.21 g/mol
Then number of moles of diphenylacetylene =
=
= 0.002972 mol
By applying the law of calorimeter;
Heat liberated by 0.002972 mole of diphenylacetylene = Heat absorbed by
+ Heat absorbed by the calorimeter
Heat liberated by 0.002972 mole of diphenylacetylene = msΔT + cΔT
= 1369 g × 4.184 J g⁻¹°C⁻¹ × (26.05 - 22.95)°C + 916.9 J/°C (26.05 - 22.95)°C
= 17756.48 J + 2842.39 J
= 20598.87 J
Heat liberated by 0.002972 mole of diphenylacetylene = 20598.87 J
Heat liberated by 1 mole of diphenylacetylene will be =
= 6930979.139 J/mol
= 6930.98 kJ/mol
Since heat is liberated ; Then, the Molar heat of Combustion of diphenylacetylene =