Answer:fH = - 3,255.7 kJ/mol
Explanation:Because the bomb calorimeter is adiabatic (q =0), there'is no heat inside or outside it, so the heat flow from the combustion plus the heat flow of the system (bomb, water, and the contents) must be 0.
Qsystem + Qcombustion = 0
Qsystem = heat capacity*ΔT
10000*(25.000 - 20.826) + Qc = 0
Qcombustion = - 41,740 J = - 41.74 kJ
So, the enthaply of formation of benzene (fH) at 298.15 K (25.000 ºC) is the heat of the combustion, divided by the number of moles of it. The molar mass od benzene is: 6x12 g/mol of C + 6x1 g/mol of H = 78 g/mol, and:
n = mass/molar mass = 1/ 78
n = 0.01282 mol
fH = -41.74/0.01282
fH = - 3,255.7 kJ/mol
Answer:
- Part a) 0.0104 moles copper(II) nitrate.
i) 0.0418 mole Cu
ii) 0.0209 mol Ag NO₃
Explanation:
<u>1) Balanced chemical reaction (single replacement):</u>
In a single replacement reaction a more acitve metal (Cu) replaces a less active metal (Ag)
- Cu + 2 Ag NO₃ → Cu (NO₃)₂ + 2 Ag
<u>2) Mole ratio: </u>
- 1 mole Cu : 2 mole Ag NO₃ : 2 mole Ag
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<u>3) Moles of Ag</u>
- n = mass in grams / atomic mass
- atomic mass of Ag: 107.868 g/mol
- n = 2.25 g / 107.868 g/mol = 0.0209 mol Ag
<u>4) Moles of copper(II) nitrate:</u>
- Set the proportion using the mole ratio:
- 2 mole Ag / 1 mole Cu (NO₃)₂ = 0.0209 mole Ag / x
- Solve: x = 0.0209 / 2 mole Cu (NO₃)₂ = 0.0104 moles Cu(NO₃)₂
That is the answer of part a: 0.0104 moles copper(II) nitrate.
<u>5) Moles of each reactant</u>
i) Cu:
- Set a proportion using the theoretical mole ratio
1 mole Cu / 2 mole Ag = x / 0.0209 mol Ag
- Solve for x: x = 0.0209 / 2 mole Cu = 0.0418 mole Cu
ii) Ag NO₃
- Set a proportion using the teoretical mole ratio
2 mole Ag NO₃ / 2 mole Ag = x / 0.0209 mole Ag
- Solve for x: x = 0.0209 mol Ag NO₃
Science doesn't make moral judgments, doesn't make aesthetic judgments, doesn't tell you how to use scientific knowledge, doesn't draw conclusions about supernatural explanations. So that's why I think it has limitations.
5.22*22^3 should be the answer
NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa
NaOH + CH3COOH → CH3COONa + H2O
Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH
Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH
These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L
Molarity of CH3COOH = 0.0106/0.071 = 0.1493M
CH3COONa = 0.0076 / 0.071 = 0.1070M
pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74.
pH using Henderson - Hasselbalch equation:
pH = pKa + log ([salt]/[acid])
pH = 4.74 + log ( 0.1070/0.1493)
pH = 4.74 + log 0.717
pH = 4.74 + (-0.14)
pH = 4.60.
