Answer:
0.109 g.
Explanation:
Equation of the reaction:
Na3PO4 + 3HCl --> 3NaCl + H3PO4
Number of moles of HCl = molar concentration × volume
= 0.1 × 0.04
= 0.004 mol.
By stoichiometry, 1 mole of Na3PO4 neutralises 3 moles of HCl. Therefore, number of moles of Na3PO4 = 0.004/3
= 0.0013 mol
Mass of Na3PO4 = molar mass × number of moles
= 0.0013 × 164
= 0.219 g
Since 50% of Na3PO4 was present in the sample. Let 100 g be the total mass of the substance
= 0.219 × 50 g/100 g
= 0.109 g.
Answer and Explanation:
For the following balanced reaction:
PCl₅(g) ↔ PCl₃(g) + Cl₂(g)
We can see that all reactants and products are gases, so it is an homogeneous equilibrium. The expression for the equilibrium constant Kp can be written from the partial pressures (P) of reactants and products as follows:

Where PPCl₃ is the partial pressure of PCl₃ (reactant), PCl₂ is the partial pressure of Cl₂ (reactant) and PPCl₅ is the partial pressure of PCl₅ (product).
Explanation:
21. The given molecule for cracking is tetradecane.
On cracking it forms one mole of decane (C10H22) and two moles of ethene gas.
The chemical equation is shown below:

22. The essential condition for the formation of an ester is the reaction of alcohol and acid in presence of concentrated sulfuric acid.
Thus among the given options, the first option is the correct one.
23. Isomers of butanol are shown below:
It is 2-butanol.
The position of -OH group changes to the second carbon.
Answer:
None of the options are correct.
Explanation:
1) when the temperature of the solution is increased the solubility of the gas in the liquid decreases , hence option 1 is incorrect.
2)The heat released by the dissolution of an ionic compound in water is heat of hydration of the compound and is independent of the initial temperature of the solution.
3) The solubility of a liquid in water is not affected significantly by the pressure changes in the system as gases only have a significant cahne in solubility with change in pressure.